vortex-l  

[Vo]:Capturing CO2 ?

Jones Beene
Sun, 27 Apr 2008 08:56:05 -0700

Among the most brain-dead of all the environmental
proposals being floated around to combat greenhouse
gases, is the kind of "carbon sequestration" where CO2
is pumped into the earth... this is beyond silly for
so many reasons... But here is an interesting
development:

http://www.sciencedaily.com/releases/2008/04/080424103217.htm

... which is a highly energy-efficient method of
converting carbon dioxide (CO2) into marketable
chemical compounds- such as cyclic carbonates.

The technique relies upon the use of a catalyst to
force a chemical reaction between CO2 and an epoxide 

http://en.wikipedia.org/wiki/Epoxide

Epoxides are cheap, but not that cheap. However, this
kind of process could be a method which is an actual
money-maker for the grid plant, and not an added cost
to the consumer.

Furhtermore, coal itself is much cheaper than
epoxides, even after the recent run-up in price, and
if the power-plant is burning coal anyway, then the
prospect of removing some of most of the CO2 with
*more coal* is intriguing....

...it sounds crazy at first; since more coal could be
required for removing CO2 than what is burned, until
you think about the possible advantages. 

Many plastics, those high tonnage varieties currently
being made from petroleum, are costly, about 15 times
more costly per pound than is coal - and could
possibly be made from CO2+coal at a huge profit to the
power plant- which would be a win-win situation...
since it would reduce the demand for petroleum and
reduce the emissions of CO2 at the same time.

I wonder if organic chemists, those who are not on the
payroll of the PetroMafia, are already looking
seriously at this possibility, especially for the
ether-based polymers, or those from polyethylene
glycol

http://en.wikipedia.org/wiki/Polyethylene_glycol

It is so obvious (as a concept) that it must be
already R&D in progress, or already proved not to be
feasible, even with the advanced catalysts.

Jones