Hi Digby,

Just a hunch that it is sampling problem.  When dealing with course gold 
particles a representative sample size is rarely practical.  Without knowledge 
of gold particle size and sub-sample/analyte mass it is hard to make this 
judgement. 

As you point out, the sub-sample values should have a normal distribution.  
Increasing the number of samples (n) would help.  Eight samples is unlikely to 
be enough to characterise what is probably a highly variable distribution.

Regards

David Reid

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