Composts do increase soil pH. Organic matter and
manure can , on the other hand decrease pH by increasing
its acidity. Compost is stable organic matter and has lots
of organic compounds that do have a buffer effect in soil
pH ( they resist to sudden changes in soil pH).
Compost contributes with some Calcium, Magnesium, Potassium
and also Sodium. All those cations can influence soil pH with
Sodium and Potassium being the ones that would influnce pH
the most.
I believe that the effect on soil pH is also an indirect one by the increased
microbial activity leading to the release of blocked minerals specially
calcium from tricalcium phosphates.
 
 
Jose
 
----
Gil,
The vineyard in question is on acid basalt derived soils with pH  around 5.5 under normal treatment and has skipped to 6.1 under compost.Interesting to note that most soil cations have also gone up and their substition for hydrogen may be the reason for the pH in crease.  The vineyard was established with 3 tonne per hectare lime application and experienced very little soil pH increase.  The compost  cost AUS $15 per cubic metre and is  much cheaper than lime.
I am trolling through petiole analysis from samples taken at the same time to see if any of the increased soil nutrients are also showing highs in the vine.
I have followed the cation balancing discussion, Albrecht etc, with tremendous interest and wonder if any one else has come up with why compost should effect soil pH?  At Uni I was told that the addition of organic material would lead to an increase in acids used by fungi to digest material and decrease soil pH leading to peat bog idea of high OM soils being acidic by nature.  But what is high?  The soils under compost have  only 2 - 3 % OM, what outcome would you get as OM approaches 5 -10%? 
Cheers JL

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