Hi Everyone
New 'Layered-layered' Materials For Rechargeable Lithium Batteries

- Researchers at the Department of Energy's Argonne National Laboratory
have developed a new approach to increasing the capacity and stability
of rechargeable
lithium-ion batteries.
The technology is based on a new material for the positive electrode
that is comprised of a unique nano-crystalline, layered-composite
structure.

Argonne's strategy uses a two-component "composite" structure -- an
active component that provides for charge storage is embedded in an
inactive component
that stabilizes the structure.

In recent tests, the new materials yielded exceptionally high
charge-storage capacities, greater than 250 mAh/g, or more than twice
the capacity of materials
in conventional rechargeable lithium batteries. Theories explaining the
high capacity of these manganese-rich electrodes and their stability
upon charge/discharge
cycling will be discussed at the Electrochemical Society meeting.

In addition, by focusing on manganese-rich systems, instead of the more
expensive cobalt and nickel versions of lithium batteries, overall
battery cost
is reduced.

Rechargeable lithium-ion batteries which would incorporate the new
materials with increased capacity and enhanced stability could be
expected to be used
in a diverse range of applications, from consumer electronics such as
cell phones and laptop computers, to cordless tools and medical devices
such as cardiac
pacemakers and defibrillators. In larger batteries, the technology could
be used in the next generation of hybrid electric vehicles and plug-in
hybrid
electric vehicles.

 Details of the new developments will be presented on Tuesday, May 8 at
the 211th Meeting of The Electrochemical Society, being held in Chicago,
May 6-10.

The presentation on "Anomalous Capacity and Cycling Stability of
Layered-Layered Electrodes in Lithium Batteries" by Argonne researchers
Chris Johnson,
Naichao Li, Christina Lefief, Jeom-Soo Kim, Jeremy Kropf, John Vaughey,
and Michael Thackeray, will be given by Chris Johnson.

Funding for the work was provided by the U.S. Department of Energy's
Office of Energy Efficiency and Renewable Energy FreedomCAR and Vehicle
Technologies
Program.

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