http://www.spacedaily.com/news/solarcell-03e.html

Princeton electrical engineers have invented a technique for making solar
cells that, when combined with other recent advances, could yield a highly
economical source of energy.
The results, reported in the Sept. 11 issue of Nature, move scientists
closer to making a new class of solar cells that are not as efficient as
conventional ones, but could be vastly less expensive and more versatile.
Solar cells, or photovoltaics, convert light to electricity and are used to
power many devices, from calculators to satellites.

The new photovoltaics are made from "organic" materials, which consist of
small carbon-containing molecules, as opposed to the conventional inorganic,
silicon-based materials. The materials are ultra-thin and flexible and could
be applied to large surfaces.

Organic solar cells could be manufactured in a process something like
printing or spraying the materials onto a roll of plastic, said Peter
Peumans, a graduate student in the lab of electrical engineering professor
Stephen Forrest. "In the end, you would have a sheet of solar cells that you
just unroll and put on a roof," he said.

Peumans and Forrest cowrote the paper in collaboration with Soichi Uchida, a
researcher visiting Princeton from Nippon Oil Co.

The cells also could be made in different colors, making them attractive
architectural elements, Peumans said. Or they could be transparent so they
could be applied to windows. The cells would serve as tinting, letting half
the light through and using the other half to generate power, he said.

Because of these qualities, researchers have pursued organic photovoltaic
films for many years, but have been plagued with problems of efficiency,
said Forrest. The first organic solar cell, developed in 1986, was 1 percent
efficient -- that is, it converted only 1 percent of the available light
energy into electrical energy. "And that number stood for about 15 years,"
said Forrest.

Forrest and colleagues recently broke that barrier by changing the organic
compounds used to make their solar cells, yielding devices with efficiencies
of more than 3 percent. The most recent advance reported in Nature involves
a new method for forming the organic film, which increased the efficiency by
50 percent.

Researchers in Forrest's lab are now planning to combine the new materials
and techniques. Doing so could yield at least 5 percent efficiency, which
would make the technology attractive to commercial manufacturers. With
further commercial development, organic solar devices would be viable in the
marketplace with 5 to 10 percent efficiency, the researchers estimated.

"We think we have pathway for using this and other tricks to get to 10
percent reasonably quickly," Forrest said.

By comparison, conventional silicon chip-based solar cells are about 24
percent efficient. "Organic solar cells will be cheaper to make, so in the
end the cost of a watt of electricity will be lower than that of
conventional materials," said Peumans.

The technique the researchers discovered also opens new areas of materials
science that could be applied to other types of technology, the researchers
said. Solar cells are made of two types of materials sandwiched together,
one that gives up electrons and another that attracts them, allowing a flow
of electricity.

The Princeton researchers figured out how to make those two materials mesh
together like interlocking fingers so there is more opportunity for the
electrons to transfer.

The key to this advance was to apply a metal cap to the film of material as
it is being made. The cap allowed the surface of the material to stay smooth
and uniform while the internal microstructure changed and meshed together,
which was an unexpected result, said Forrest. The researchers then developed
a mathematical model to explain the behavior, which will likely prove useful
in creating other micromaterials, Forrest said.

"We've shown a very new and general process for reorganizing the morphology
of materials and that was really unanticipated," Forrest said.



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