Hi, is that on a standalone Guix system or on another distribution?
Please try to find a file named "org.freedesktop.PolicyKit1.service" in /gnu/store and then find a line like the following in it: Exec=/gnu/store/xfysy3c824m4z8b07sbiangp7i2xfh6s-polkit-0.113/lib/polkit-1/polkitd --no-debug Then please try to invoke that polkitd manually as root. Does it also fail?
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