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A related issue and perhaps useful information ... 

We have had a couple of times with dry shippers when crystal surface
icing has been a problem. We wondered if the shipper had been opened on
route or air pressure differences had allowed moist air to enter when
the aircraft landed. Most of our experiments are now robotic so we don't
get a chance to examine the shippers at the other end.  Washing crystals
in liquid nitrogen at the beamline removes most of the problems but it
is an extra step that eats into data collection time. 

To try and get round this we found that it is possible to ship dry
shippers wet, at least within the US, and it is not significantly more
expensive. I talked to FedEx and have now taken an online FedEx Ground
course (for $150) on HazMat shipping. FedEx asks you to fill out a
little more paperwork (three forms), notifies your local office and then
you can ship quite easily (in theory). We are just about to try our
first example.

Course details are at https://prosperitylms.com/req/fedex_student/

After talking to an agent at our local FedEx he recommended putting a
label on the top of the dewar inside the shipping box saying something
to the effect that of "Dewar contains sample at cryogenic temperature -
do not open". They are more used to shipping samples for livestock
breeding than crystals and this makes the contents "less interesting" -
quoting directly. Our local office gets 30-40 of these a day and crystal
samples only about twice a month.  

Liquid nitrogen can also be shipped by air in a dry shipper. SSRL
routinely ships dry shipper back wet. To do this through FedEx requires
a longer training course, 3 days for $650, with details at:
http://www.fedex.com/us/services/options/express/dangerousgoods/seminars
.htm
(and more paperwork). Basically FedEx need a trained name who has
verified the material (Nitrogen, refrigerated liquid, Nonflamable,
UN1977, HazMat class 2.2, ERG no 120). 

If the ground shipment with liquid is sufficiently better than the
equivalent dry shipper by air we will have someone take this course. A
quick and dirty comparison of ground versus air for dry-shippers showed
little difference in icing but a lot of difference in worrying where the
truck was for a few days. 

You may already have someone in your shipping and receiving department
able to do this - the courses are general courses for HazMat/Dangerous
goods shipping not just liquid nitrogen. 

I'd be interested in hearing if anyone has had experience with shipping
samples in liquid N2 compared with dry shippers?  Is it worth the extra
effort beyond simply preventing surface icing?

Cheers,

Eddie



Edward Snell Ph.D.
Assistant Prof. Department of Structural Biology, SUNY Buffalo,
Hauptman-Woodward Medical Research Institute
700 Ellicott Street, Buffalo, NY 14203-1102
Phone:     (716) 898 8631         Fax: (716) 898 8660
Email: [EMAIL PROTECTED]  Telepathy: 42.2 GHz
 
Heisenberg was probably here!
 


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