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I know this doesn't address your actual question, but since you say the
rods are hollow for "most" of their length, is there a not-hollow part
that might be large enough to shoot with a narrow synchrotron beam? Your
crystals sound similar to some that I worked with, although in my case
the hollow imperfections did not extend so deeply, and I found that I
could shoot through the middle of the rod avoiding the hollow area, and
get very nice diffraction.


Evette S. Radisky, Ph.D.
Assistant Professor and Associate Consultant II
Mayo Clinic Cancer Center
Griffin Cancer Research Building, Rm 310
4500 San Pablo Road
Jacksonville, FL 32224
(904) 953-6372 (office)
(904) 953-2857 (lab)

-----Original Message-----
From: [EMAIL PROTECTED] [mailto:[EMAIL PROTECTED] On Behalf Of
Patrick Loll
Sent: Tuesday, December 05, 2006 1:32 PM
To: [email protected]
Subject: [ccp4bb]: reducing crystal imperfections

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We have a system where we can produce rod-shaped crystals that show a
classic depletion imperfection--the rods are essentially hollow for most
of their length, suggesting that growth is proceeding in this direction
more rapidly than fresh protein can diffuse into the area (picture a
long hexagonal rod with a perfect conical hole bored into one end,
extending for most of the rod's length).

Simple-minded optimization experiments (e.g., [PEG] vs. [salt] vs. pH)
have clear-cut effects on nucleation, but don't seem to alter crystal
shape, which I interpret as meaning that growth occurs rapidly once
nucleation has taken place.

What are peoples' thoughts on improving the morphology?  We're currently
exploring whether additives can selectively poison growth along the long
axis, but I'd be curious to hear other ideas.  For example, might gels
help, or are they mainly effective in controlling nucleation?

They ARE pretty cool looking.  I wonder if there's a market for
nanovases...

Pat

------------------------------------------------------------------------
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Patrick J. Loll, Ph. D.                                         (215)
762-7706
Associate Professor                                     FAX: (215)
762-4452
Department of Biochemistry & Molecular Biology Director, Biochemistry
Graduate Program Drexel University College of Medicine Room 10-102 New
College Building
245 N. 15th St., Mailstop 497
Philadelphia, PA  19102-1192  USA

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