PTM is very much possible in E. coli - just not every kind of PTM. To my
knowledge, serine, threonine, and tyrosine phosphorylation is not in the
normal genetic arsenal of this organism unless you introduce appropriate
kinases artificially (such as by means of expression of a foreign gene or
via modification of a suitable E. coli enzyme).

If you express a kinase, there are good chances that it will phosphorylate
itself and many other intracellular proteins.

Other than that, you may encounter instances of histidine phosphorylation.

Artem

-----Original Message-----
From: CCP4 bulletin board [mailto:[EMAIL PROTECTED] On Behalf Of
Narayanan Ramasubbu
Sent: Friday, October 26, 2007 6:31 PM
To: [email protected]
Subject: [ccp4bb] Is phophorylation possible in E. coli expression system?

Dear All:
This is not crystallography related and does not belong to this group, 
but I would like to pose this to all who are working with proteins 
expressed in an E. coli BL21 (DE3) or Rosetta. Is it possible for a 
protein to be phosphorylated during expression? At least my 
understanding was that post-translational modifications are not 
possible in E. coli. However, recently we expressed a protein and 
noticing that there are lot of potential tyrosine phosphorylation 
sites, we checked the expressed protein on a gel using a stain that 
detect phosphates. (Please do not say Are you crazy? Why would you 
check.. etc). Lo and behold, there lights up the band. Hence my 
question to you all. I could not google or mine from PubMed specific 
references that exist regarding this. Please enlighten me.
Thanks a lot.
Also, I would like to take this opportunity to thank everybody for all 
the help whenever  ask some off-topic question like ths.
Subbu

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