Hi,

Just a newbie question:

Could someone explain what might have gone wrong in this case? I guess
the structure factors should not change anyway! I am a bit confused
because I have used solve resolve several times for experimental
phasing, never had such a problem, on the other hand, have not heard
about density modification for MR apart from one posting (from Prof.
Lawrence Perl I think).

Is it by any chance that the FOMs were highly overestimated and that
creates a problem with Maximum likelihood? That sort of reminds me of
what I had heard for SHARP-solomon in a couple of instances..

Any insight would be highly appreciated..
Regards, Partha


On Fri, Mar 28, 2008 at 2:35 PM, Garib Murshudov <[EMAIL PROTECTED]> wrote:
> make sure that you are using the original observation (Fobs and
>  corresponding sigmas) not that produced by density modification (e.g.
>  solve resolve) programs.
>
>  Garib
>
>
>
>  On 28 Mar 2008, at 10:43, stefano ricagno wrote:
>
>  > Dear CCP4bb readers,
>  > this is my problem:
>  > I solved a structure by MR: the solution was easily found (molrep,
>  > phaser and balbes found always the same one), density looked
>  > generally reasonable (however in several places it was dubious) but
>  > R/Rfree were stuck at 42/47%.
>  > Then I tried some density modifications, resolve worked
>  > spectacularly the density became wonderful and several parts which
>  > were not in the model appeared.
>  > So I finished to build the model and everything looked good.
>  > The problem is now for a structure at 2.8 Å resolution I have R/
>  > Rfree of 8/9.5% respectively, which is clearly too good. Checking
>  > refmac log file it looked to me that refmac uses all the
>  > reflections in the .mtz file (that is as many reflections as before
>  > the resolve run).
>  > Ideas?
>  >
>  > thanks
>  >
>  > Stefano
>  >
>  > ps this is my last refmac:
>  >
>  > 2 mol in the AU, no NCS used, weighting term 0.01, no tls.
>  >
>  >    Ncyc    Rfact    Rfree     FOM      -LL     -LLfree  rmsBOND
>  > zBOND rmsANGL  zANGL rmsCHIRAL $$
>  > $$
>  >        0   0.0943   0.1051   0.937    102149.    5673.2   0.0070
>  > 0.298   1.202  0.546   0.077
>  >        1   0.0910   0.1024   0.940    101442.    5642.4   0.0058
>  > 0.252   1.091  0.481   0.073
>  >        2   0.0898   0.1019   0.940    101221.    5634.0   0.0055
>  > 0.238   1.061  0.461   0.072
>  >        3   0.0891   0.1016   0.941    101080.    5628.8   0.0052
>  > 0.226   1.045  0.451   0.072
>  >        4   0.0884   0.1011   0.942    100947.    5622.7   0.0050
>  > 0.217   1.033  0.445   0.071
>  >        5   0.0877   0.1006   0.942    100824.    5617.0   0.0049
>  > 0.211   1.024  0.440   0.071
>  >        6   0.0872   0.1001   0.943    100708.    5611.4   0.0047
>  > 0.205   1.016  0.436   0.070
>  >        7   0.0866   0.0997   0.943    100593.    5606.5   0.0047
>  > 0.202   1.008  0.432   0.070
>  >        8   0.0861   0.0992   0.944    100483.    5601.5   0.0046
>  > 0.199   1.002  0.429   0.069
>  >        9   0.0857   0.0989   0.944    100391.    5597.5   0.0045
>  > 0.196   0.996  0.426   0.069
>  >       10   0.0852   0.0985   0.944    100313.    5593.5   0.0045
>  > 0.193   0.990  0.423   0.068
>  >
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