I would be very careful about any bond to As. I would imagine such
bonds would be very susceptible to radiolysis with typical radiation used
in the diffraction data collection. Have you performed some
diffraction experiments of various time lengths (or flux) and seen what
happens around this region of the electron density map?
Jim
On Wed, 6 Jul 2011, conan???? wrote:
Dear All,
Hi. I was asked in a manuscript revision to discuss about the possible
effects of
Fourier transformation ripples on the crystallographic results. Specifically,
the reviewers
question whether ripples may affect on the electron density around heavy metal
center which has
a Mo-S-As connection. From which angle or in which way this problem should be
addressed most
convincingly ?
Thank you for any suggestion.
Best,
Conan
