Are you referring to the I3C magic phasing triangle by any chance? Beck,
et al Acta Cryst D 61(?) (2008) is the reference I think.



Good luck!

Bryan



From: CCP4 bulletin board [mailto:[email protected]] On Behalf Of
Richard Gillilan
Sent: Friday, November 30, 2012 5:21 PM
To: [email protected]
Subject: Re: [ccp4bb] Izit dye stained crystal



We've found that high PEG concentration seems to compete with dye
binding, so I'm not surprised your didn't see good uptake.

I doubt the anomalous signal is from the dye ... if you calculate the
molar dye concentration you would need to have significant occupancy in
the lattice, you'll probably find that the crystals would look almost
black ... unless there was a color change.



I recall seeing a poster at the annual ACA meeting 3-4 years ago maybe,
in which somebody was using polybrominated or polyiodinated aromatics to
both dye the crystals and phase the structures at once. In fact, I think
we gave the poster an award for that. I don't have my past notes handy
to remember, but could look it up if you're interested.



Richard Gillilan

MacCHESS





On Nov 30, 2012, at 4:19 PM, Sarathy Karunan Partha wrote:





Dear all,



We did some Izit dye staining to test our crystal (salt or protein) and
we observed that the crystal didn't take up the dye well. But, showed
nice protein diffraction (home source KCr 2.2909 A) and we collected a
dataset (360 frames, 1o osc, 5 min exposure) on this dye stained
crystal. The data collection statistics looks great and most
interestingly we saw some anomalous signal for this data (see attached
XSCALE.LP).



This protein was crystallized in 0.2 M Ca acetate, 30 % PEG 400 pH 4.5.
Izit dye is basically methylene blue which contains a sulfur atom
(phenothiazine ring) and also has some basic dimethylamio groups. Our
protein has many acidic residues that could enhance binding of this
basic dye.We think the anomalous signal could be from this dye and the
heavy atom search with autoSHARP and Phenix autosol is suggestive of 4
sulfur atoms.



Did anyone come across similar situation with using this dye and also
welcome any suggestions about using this data for S-SAD phasing.





Thanks,

Sarathy

<XSCALE.INP>




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