Just a thought—is the reducing agent changing pH? Also, is your protein a 
metal-binder?

JPK

From: CCP4 bulletin board [mailto:[email protected]] On Behalf Of zhuqing 
ouyang
Sent: Monday, May 12, 2014 12:33 PM
To: [email protected]
Subject: [ccp4bb] off topic, complex precipitate in reducing reagents

Hi all, I came across a strange problem.
When I purify a protein complex, let's say AB, it will precipitate when I add 
reducing reagent like DTT or TCEP in the gel filtration buffer, or if I don't 
include any reducing reagent running column, I take the peak fractions and 
supplemented with DTT or TCEP, it will also precipitate. And the precipitation 
is irreversible when I change buffer to non-reducing reagent buffer.
But when I purify A or B alone, they don't have this problem.
Anyone have some clues for this observation?
Thanks a lot.

zhuqing

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