Hi Xiao,
what you run into here is a aqueous two phase system, phosphate and PEG tend to 
form that, see wikipedia entry.

35% PEG 3350 is not a bad cryo, the combination with phosphate is just 
unfortunate. Any chance you can replace with a different salt or buffer? I 
don't know if adding small PEGs will help.
Glycerol, MPD, sugars or oils might be helpful.

Cheers,
Jan
--
Jan Abendroth
Beryllium
Seattle / Bainbridge Island WA, USA
home: Jan.Abendroth_at_gmail.com
work: JAbendroth_at_be4.com
http://www.be4.com

On Oct 13, 2014, at 6:08 PM, Xiao Xiao <[email protected]> wrote:

> Hi Mayer and Jason,
> 
> Thanks for your quick reply! I read from Hampton that for PEG smaller than 
> 5K, directly increasing its concentration is a way of making cryo. But you're 
> right, glycerol or PEG400 will be a good way and might be easier.  I'll try 
> that first.
> 
> Thanks a lot!
> 
> Best,
> Xiao
> 
> 2014-10-13 17:59 GMT-07:00 Mayer, Mark (NIH/NICHD) [E] <[email protected]>:
> Try either glycerol or PEG 400.
> Increasing concentration of 'high' MW PEG is not a good strategy.
> 
> ________________________________________
> From: Xiao Xiao [[email protected]]
> Sent: Monday, October 13, 2014 8:51 PM
> To: [email protected]
> Subject: [ccp4bb] A quick question about making PEG cryo-protectant
> 
> Hi,
> 
> Since my crystallization condition contains PEG, I am trying to use PEG as 
> one of my cryo for testing. For example, one crystallization condition is 
> 0.2M Na2PO4, 20%PEG3350. I want to make 0.2M Na2PO4 and 40% PEG3350 as 
> cryoprotectant. When I added 200ul salt from 1M stock, and 800ul PEG from 50% 
> stock, mixed them, seems they stayed as emulsion (confirmed by microscope), 
> no matter how I pipette or vortex them. I tried to incubate it at 40degree, 
> seems it got worse.
> 
> I am now trying to re-make the cryo from solid reagent, not solution stock. 
> Will this be helpful? Or is there any other trick?
> 
> I will really appreciate!
> 
> Best,
> Xiao
> 

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