Dear all,

I am working on my molecule, but after running

Refmac5 restrained refinement the bonding distances and angles are broken.

I used Phenix to create the ligand and used Coot to place the ligand
into the correct location in the molecule, merged the ligand and
molecule coordinates, and saved the file. Then I went to run
restrained refinement on
the merged coordinates using the cif file provided from the phenix to
the refmac library,the rest of the settings were set at the defaults.
During fitting the model in the 2Fo-Fc map of the ligand there were no
issue, but it fitted well and after refinement of the same, the bond
breaks and
distorted as observed in coot. The resolution is 1.6 Ang.
phosphate linkage bond is broken. What could be the best possible
reason for this and what can be solution for this ? Could you please
suggest what should I do for a complete model for the ligand ? I would
like to run a round of restrained refinement without breaking any
geometric restraints that should be imposed on my ligand.

Thank you for your help in advance,


Jeorge

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