Hi,

I think it was Ian Tickle who worked out the statistical error in R-free that 
arises from taking different random samples, though I can’t track down the 
publication quickly. Anyway, the take-home from this is that you don’t expect 
all free sets to give the same R-free, and you shouldn’t over-interpret small 
differences in R-free.

Does anyone have the citation for this?

Best wishes,

Randy

> On 23 Jun 2025, at 15:55, Oganesyan, Vaheh <[email protected]> 
> wrote:
> 
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> div.WordSection1 {page:WordSection1;} --> Hi all,
>  I’ve spent some time going through different flags for free reflections for 
> (somewhat stupid) reason to get lower Rfree. I made sure all different flags 
> were used only for each of sets of refinement. I wanted to satisfy my inner 
> belief that it doesn’t matter which flag is used (between 0 and 19). To be 
> short: I failed.
>  Free reflections have been chosen “randomly”, no suspicion there. However, 
> there was clear difference at the end. The difference was about 2-3% 
> difference in Rfree value. This tells me that the randomness has some sort of 
> rule, which makes “random” choice not so random. Having found this I also 
> tried to see “a rule” that breaks this randomness, like even numbers, odds, 
> etc. I did not. Because this was only on few cases I won’t even try to 
> connect it to # of molecules per AU, or SG. For each structure (I tried this 
> for 2-3 structures about 10 years ago) it was a different flag.
> I’m not sure if DCC also is looking through different flags, but at the end 
> it finds the best, making these exercises unnecessary. 
> Sorry, cannot present a case. Was too long ago.
>  Vaheh Oganesyan, Ph.D.<image001.png>R&D | Biologics Engineering
> One Medimmune Way, Gaithersburg, MD 20878
> T:  301-398-5851
> [email protected]
>     From: CCP4 bulletin board <[email protected]> On Behalf Of Randy John 
> Read
> Sent: Monday, June 23, 2025 10:29 AM
> To: [email protected]
> Subject: Re: [ccp4bb] free R in shells
>  Hi Ben,
> 
> I would be very interested if you have a case where it makes a difference to 
> do this. At one point I was convinced that it had been important when we were 
> working on the structure of a Shiga-like toxin bound to trisaccharide (1bos), 
> with four pentamers in the asymmetric unit. However, Pavel Afonine challenged 
> me to show that the free set was less biased when chosen in shells than when 
> chosen randomly, and even in that relatively extreme case I couldn’t see 
> evidence of it. So it’s probably not worth the bother. Also, if you select 
> the free set randomly, it’s distributed over the same resolutions as the 
> working data, which arguably is important when you’re using it to calibrate 
> the sigma(A) estimates for likelihood targets.
> 
> Best wishes,
> 
> Randy
> 
> > On 23 Jun 2025, at 12:35, Ben Bax <[email protected]> wrote:
> >
> > Hi,
> > How do you select R-free in shells with CCP4?
> > Thanks, Ben Bax
> >
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> -----
> Randy J. Read
> Department of Haematology, University of Cambridge
> Cambridge Institute for Medical Research Tel: +44 1223 336500
> The Keith Peters Building
> Hills Road E-mail: [email protected]
> Cambridge CB2 0XY, U.K. www-structmed.cimr.cam.ac.uk
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-----
Randy J. Read
Department of Haematology, University of Cambridge
Cambridge Institute for Medical Research     Tel: +44 1223 336500
The Keith Peters Building
Hills Road                                                       E-mail: 
[email protected]
Cambridge CB2 0XY, U.K.                              
www-structmed.cimr.cam.ac.uk


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