Did you consider partial occupancy and or a mixture with
phosphorylation?
The residue SEP will solve your problem with covalent modification and
its cif file can guide you in setting up a cif file for the vanadate
serine modification (just replace all P with V and change the SEP to
SEV or whatever). 

Greetings
  Gottfried


Am Dienstag, den 15-07-2025 um 04:52 schrieb Manjula Ramu:






Dear CCP4 community,







 I am currently working on a structure that includes a vanadate
(VO₄) moiety, and I am facing challenges with properly modeling and
refining it in Coot and Refmac.







Specifically, I would appreciate guidance on the following:



– The best way to fit vanadate into the electron density (I see
negative density in the same position)



– How to handle potential covalent interactions with active site
residues (e.g., serine)







Any suggestions, relevant examples (PDBs or procedures), or workflow
tips would be greatly appreciated. I am attaching the screenshots for
you to look over.







Thank you in advance for your support and expertise.


















----------------------------------------------------



Thanks and Regards,



Manjula 







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