You are cordially invited to join the Center for Biomolecular Structure Lecture 
Series ………..

Saumen Chakraborty

The University of Mississippi

WEDNESDAY, June 24, 13:30 (EDT)


"Artificial Metalloproteins to Harvest Solar Energy and Small Molecule 
Activation"

Register in advance for this meeting:

   https://bnl.zoomgov.com/j/1608968233?pwd=zJn5FYvcPM58P1CfantsS6bhTiMIIW.1
      
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Abstract: Metalloenzymes catalyze complex reactions with unprecedented 
efficiency. These enzymes are promising candidates for various biotechnological 
applications, including producing alternative fuels and pharmaceuticals. 
Oftentimes, the innate complexity of these metalloenzymes prohibits a true 
appreciation of their full capability and a detailed understanding of their 
structure-function relationships. One approach to alleviating this issue is to 
design artificial metalloenzymes (ArMs) that still contain the metal of 
interest in a biomolecular environment, allowing the chemistry to be performed 
in aqueous media. The protein scaffold prevents unwanted side reactions. In 
addition, the protein environment allows one to alter outer sphere interactions 
to fine-tune their reorganization energies and reactivity. In this seminar, I 
will present two complementary approaches to designing Ni and Cu-containing 
ArMs – artificial hydrogenases and artificial C-H peroxidation catalysts 
utilizing protein reengineering and de novo protein design approaches.


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