A few suggestions:
Try feeding a video source through the video inputs. This bypasses the tuner/IF section. If the problem is still there, then the tuner is fine. Concentrate in the neighborhood of the video processor IC.
From the description of the symptoms, looks like a component with a thermal breakdown. Get a spray can of component freezer. When the symptoms reoccur spray the suspect components one at a time until the color comes back. Warm up the area with a hair dryer and repeat the procedure until you nail down the bad boy.
It could also be a cold solder joint somewhere just barely making contact when the TV is cold. Tap the suspect area with a long piece of plastic and watch what happens with the image.
 
Good luck.
Tony

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