I hit the same problem after "ubuntu" (unity-3d) profile was BROKEN here.
To workaround this, I used "unity-2d".

compiz-session-ids are stored at different places.
unity-2d: ~/.compiz/session/
ubuntu (unity-3d): ~/.compiz-1/session/

When switching at the X-login-manager (LightDM) from "unity-2d" to "ubuntu" 
(unity-3d) you will hit the warning.
NOTE: ~/.compiz/ dir gets removed.

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https://bugs.launchpad.net/bugs/344053

Title:
  I/O warning : failed to load external entity

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