Email digest for the Global Conservation Forum (ConsDistList) egroup.
------------------------------------------------------------------------------------------------------------

 1. Lecturer/ Senior Lecturer/ Reader in the Conservation of Buddhist Heritage 
at The Courtauld, London

 2. RE: Cellulose Nitrate Coatings for Protecting Silver - Frigilene

 3. RE: Cleaning Gravestones with D/2 Biological Solution

 4. RE: Cleaning Gravestones with D/2 Biological Solution

 5. RE: Cleaning Gravestones with D/2 Biological Solution

 6. There's still time to register for APOYOnline's 5th Regional Conference 
"Sustainable Connections for Cultural Heritage"

------------------------------------------------------------------------------------------------------------

1.From: Clare Richardson
 Posted: Friday May 30, 2025  8:00 AM
 Subject: Lecturer/ Senior Lecturer/ Reader in the Conservation of Buddhist 
Heritage at The Courtauld, London
 Message:  Lecturer/ Senior Lecturer/ Reader in the Conservation of Buddhist 
Heritage  
   
   Salary    52,216 per annum including London Allowance (subject to the 
academic level in line with our criteria).  Contractual hours 35  Basis Full 
Time  Job category/type Conservation  Date posted 14/05/2025  Job reference 230 
     Shape the Future of Conservation at The Courtauld  We invite outstanding 
academics to join our faculty as a Lecturer, Senior Lecturer or Reader in 
Conservation of Buddhist Heritage, contributing to world-class teaching and 
research within our renowned institution.  As part of The Courtauld, you will 
be at the forefront of shaping our Conservation team for students and scholars 
alike.  
 WhatWe'reLookingFor  We are seeking a passionate Lecturer, Senior Lecturer or 
Reader to expand and deepen The Courtauld's curriculum and research impact, 
specifically in the Conservation of Buddhist Heritage.  
 RoleDetails  Contract basis: Permanent|Full-time: 35 hours | Location: Hybrid 
/ Onsite | 52,216 per annum including London Allowance (subject to the academic 
level in line with our criteria).  
   AboutTheCourtauld  For nearly a century, the Courtauld Institute of Art has 
been a unique centre of expertise. A world-leading institute renowned for 
ground-breaking scholarship in art history, conservation and curation. Home to 
one of the largest communities of art historians  and conservators in the 
world. With a gallery that cares for one of the UK's finest art collections at 
its heart.  The Courtauld is one of the foremost centres in the world for 
education and research in conservation. We run three-year MAs in the 
conservation of easel paintings (18 students) and wall paintings (6-12 
students) and a 12-month MA in Buddhist Art History and  Conservation (12 
students, jointly taught with the History of Art department).  
   KeyResponsibilities  - Hold a recognised qualification in conservation or 
equivalent experience  - Understand developments in conservation theory and 
practice related specifically to wall painting conservation and the 
conservation of Buddhist sites, ideally with experience of having worked on 
Buddhist sites  - Be able to speak about your research and teach a variety of 
audiences, including students at all levels and the public.  - Have ambitious 
plans for your research and for the Robert H.N. Ho Family Foundation Research 
Centre for Buddhist Art and Conservation programme  - Be collaborative and 
enjoy working as part of a team to deliver fieldwork, teaching and research  - 
For further information, please see the Job Description and Person 
Specification.  
   WhyJoinUs?  At The Courtauld, you'll be part of a prestigious academic 
community with access to unparalleled research resources and institutional 
support. Some of our benefits include:  30 days annual leave + 6 office closure 
days 
 Research support & funding opportunities 
 Discounted Gallery Access & Reciprocal Museum Benefits 
 Hybrid working & flexible academic support 
 Wellbeing Support & Employee Assistance Programme  
   How to apply  If you are ready to make an impact at The Courtauld, we invite 
you to apply! Review the Job Description and Person Specification then take the 
first step and apply with no delay! Please note that a cover letter is required 
for this role.  
https://ce0942li.webitrent.com/ce0942li_webrecruitment/wrd/run/etrec179gf.open?WVID=7234972FGb&LANG=USA
 
<https://ce0942li.webitrent.com/ce0942li_webrecruitment/wrd/run/etrec179gf.open?WVID=7234972FGb&LANG=USA>
  
   ClosingDate:30th June 2025          InterviewDate:17th July 2025  
   The Courtauld Institute of Art is committed to fostering an inclusive 
academic environment. We actively welcome applications from candidates of all 
backgrounds.  
  
   
   Clare Richardson  
 Head of Conservation
  Department of Conservation  
 The Courtauld Institute of Art                                                 
     
 Somerset House, Strand 
 London WC2R 0RN                                                                
                                                           
 Tel: +44 (0) 20 3947 7659  
 [email protected]  
 www.courtauld.ac.uk <http://www.courtauld.ac.uk/>  
  
      Find out more about what's on at The Courtauld -  
courtauld.ac.uk/whats-on <https://courtauld.ac.uk/whats-on/?see-all>
 
 Book tickets to The Courtauld Gallery's permanent collection and temporary 
exhibitions at  courtauld.ac.uk/gallery <https://courtauld.ac.uk/gallery/>
 
 For more information on studying at The Courtauld, visit  
courtauld.ac.uk/study <https://courtauld.ac.uk/study/>
 
 Visit The Courtauld Shop for carefully curated products inspired by art and 
artists in our collection:  shop.courtauld.ac.uk <https://shop.courtauld.ac.uk/>
 
 
 
   
 

2.From: Maickel van Bellegem
 Posted: Friday May 30, 2025  8:01 AM
 Subject: RE: Cellulose Nitrate Coatings for Protecting Silver - Frigilene
 Message: 
Dear all, for the coating of silver many things have been said before. I 
believe it is important to consider it as an approach with a long term policy, 
so it is also important how the objects are displayed/ stored/ handled in the 
future. Applying frigilene or historically also called zapon-lack in some 
countries does have a fair tradition for (decorative) silverware.


The lackering as done at the V&A, I'm speaking here based on my experience 
there from about 10 years ago, does have a succes record to last about 25 years 
(i.e. the main silver gallery). Usually 2 coats are applied by brush (3 coats 
for objects displayed not in a display-case), The time inbetween applications 
can be manipulated by using a hot-air gun. That way the iridescence, any 
dripping or brushmarks can be avoided. It does indeed require experience to 
apply good coatings (and a dust free space!). I have a preference for soft-hair 
brushes (i.e. squirrel-hair but they can be difficult to source), and did use 
small amounts of acetone to dilute. Acetone would also be used to remove 
residue of old coatings. If possible, immersion in hot water followed by 
steam-cleaning was used initially. The acetone for removal would be re-used in 
multiple baths, so the most-used (or dirtiest) acetone was used for the first 
removal, then second removal with a slightly cleaner acetone, ultimately
 with new acetone for the final clean before re-application of a new coating. 


my experience with the dipping application, has only been to remove it later 
because of drips or sealed up holes and the overall appearance being 
compromised. similar for spray-application where the applications had been 
incomplete and which had been missed at the time of application.


As part of the decision-making proces apart from the ongoing care, it should 
also be considered what the overall appearance of the silver object preferably 
is, i.e. what was the original surface finish (method of polishing/ burnishing, 
blanching, oxidised, or combination with other materials?) and to what extend 
did the surface tarnish over time, and is it now desirable to also preserve 
that? So this is considered in combination with the method to remove tarnish. 
With applying a coating there is a risk over time that the tarnish will develop 
stronger at a smaller/ specific location (associated with the failure/ 
application of the coating) and result in a patch with an 'etched' appearance. 


Hope that helps, and happy to answer more questions if needed. 


Best, Maickel van Bellegem.


------------------------------
Maickel van Bellegem ACR Conservator (freelance)
Sluis (NL) and London (UK) 
+31 648775052 / +44 7890628526
[email protected]
------------------------------
-------------------------------------------
Original Message:
Sent: 05-28-2025 07:23
From: Paul Harrison
Subject:  Cellulose Nitrate Coatings for Protecting Silver - Frigilene


There is a paper by the Victoria and Albert by Simon Metcalf   their 
Conservation Journal Jan 1997  issue 22 , can Google it  other search engines 
are available I try to use Frigilene as is a cellulose nitrate which we know 
has issues of aging. I tend to use Incralac designed for copper but silver and 
copper are in many ways first and second in their column on the Periodic Table 

Simon found

point B1 unlacquered corrode in a year, lacquered in ten 

point B2 they know Frigilene 

point B3 compared with B72 Paraloid  and Covolac  results similar 

point B4 Frigilene is easy to apply 

point A1 complicated thins hard to lacquer nicely 

point A2 good lacquer is a skill 

point A3  handling wears lacquer away 

point A 4 Cellulose Nitrate  deteriorates with light and goes brown less 
protective 

point A5  emits nasty solvents ( Incralac is guilty too )


------------------------------
Paul Harrison
Glenfield
United Kingdom
------------------------------

Original Message:
Sent: 05-26-2025 21:46
From: Jingyi Zhang
Subject: Cellulose Nitrate Coatings for Protecting Silver - Frigilene

Dear colleagues,

My name is Jingyi Zhang, and I am a Conservator with the Heritage Conservation 
Centre (Singapore). 

We are currently exploring the use of cellulose nitrate coatings to protect 
silver objects in our collection. We are looking specifically at Frigilene, as 
this is the only product we can access from conservation suppliers due to 
import and shipping restrictions. 

While doing our literature review, we noted that projects such as Winterthur's 
Agateen coating program has shown to provide long-term benefits in deterring 
tarnish on silver. On the other hand, there are also several publications 
discouraging its use and highlighting various risks with such coatings (eg. 
cyanide by-products). With this in mind, we are curious to find out more about 
you/your institution's current practices with regards to coating silver – what 
product(s) are used, how is it applied (brush/spray/dip etc.), any short/long 
term observations regarding its effectiveness etc.? 

Application wise, we have been practicing applying Frigilene on silver proxy 
objects by brush and dipping. We have yet to try air brushing/spraying. From 
our current practice, we have some questions:
Any recommendations for the proportion/ratio of Frigilene to thinner to use? We 
have been trying a 1:1 ratio but tend to get iridescence when doing a brush 
application, and iridescence, pooling and drip marks when doing a dip 
application. What is the composition of the thinner? We did ask our vendor but 
did not get a response on this.  How long to wait in between coats? How many 
coats to apply?  How do you check the quality and for disruptions in the 
coating? We note that UV-fluorescent dyes can be added to the coating mixtures 
for this purpose.Any preference for brushes or bristle type? We have been using 
a mixed goat hair flat brush. 
We would appreciate any advice and useful tips on this. If direct contact is 
preferred, my email address is [email protected] <[email protected]> 
Thank you.


------------------------------
Jingyi Zhang
Conservator (Inorganic Objects)
Heritage Conservation Centre
Singapore
------------------------------


3.From: Howard Wellman
 Posted: Friday May 30, 2025  12:02 PM
 Subject: RE: Cleaning Gravestones with D/2 Biological Solution
 Message: Lorraine,

thank you for that excellent summary!  I may quote you in future!

sincerely,

Howard

-- 
Howard Wellman
Wellman Conservation LLC

-------------------------------------------
Original Message:
Sent: 5/29/2025 7:02:00 AM
From: Lorraine Schnabel
Subject: RE: Cleaning Gravestones with D/2 Biological Solution


Jim,


Rather than directly addressing your question about D/2, I would pose the more 
fundamental question that confronts architectural conservators on a daily 
basis, which is should you clean at all? Are the stones being cleaned so the 
inscriptions can be recorded? Or is there some other compelling reason for 
cleaning other than to make the cemetery "look better?" Are you able to change 
the environment such that the soiling is unlikely to return (sometimes possible 
with buildings)? Giving volunteers something to do is not a compelling reason. 


Much of the "dirt" on grave markers is biological (a biofilm), and the 
quaternary ammonium compounds in commercial biological cleaners work to varying 
degrees to remove this type of soiling. The effects of cleaning can be 
dramatic, as numerous videos on YouTube will attest. However, the long-term 
effectiveness of such cleaning products is limited, especially if no concurrent 
changes are made to the environment of the object being cleaned. The soiling 
will return, sometimes rather quickly depending on the composition of the 
biofilm and the nature of the environment. Even if you are prepared to set up a 
long-term maintenance program to repeat the cleaning as the soiling inevitably 
returns, biofilms will adapt over time such that the cleaning chemical becomes 
less effective. Use of water repellents as a means of controlling the 
environment does not have a good track record, and there is plenty of 
literature that addresses concerns surrounding application of water repellents 
to masonry. 


Also, any amount of scrubbing amounts to a type of mechanical weathering that 
will immediately or eventually cause surface loss, depending on the type and 
state of deterioration of the marker. Lichen in particular can be highly 
resistant to removal on weathered stone surfaces without some amount of 
scrubbing.


If you want to take a positive action to preserved the cemetery, consider other 
steps. Most small cemeteries have no record of burials, so creating a database 
that includes all the information on the markers and photographing them is one 
valuable effort volunteers can make to preserve a cemetery. Inputting that 
information into a resource like Find a Grave is helpful to genealogical 
researchers. Creating a map of the cemetery (useful to develop a numbering 
system for the database), including elements of the landscape, would provide a 
means of locating the stones you have documented. Historical research to flesh 
out the database can help put a face on the history of the community the people 
in the cemetery were a part of. Properly supervised, volunteers can straighten 
markers that are leaning, and re-set markers that have toppled, but this effort 
needs to be led by someone with experience in lifting and moving things that 
are both heavy and fragile, and ideally a trained conservator
 if any sort of reassembly is needed.


Maintaining the cemetery grounds is critical to their preservation--volunteers 
who are willing to hand trim around graves and use push mowers prevents the use 
of string trimmers that damage the stone and zero turn or riding mowers used by 
most landscaping companies that can cause untold damage to markers.  Money 
available for cleaning chemicals could instead be used for tree-trimming, 
something that is often needed in older cemeteries to protect markers from 
being damaged by falling tree limbs, or for repair of walls and/or fencing.


I hope any of this information is of some use. 


Kind regards,


------------------------------
Lorraine Schnabel
Schnabel Conservation LLC
[email protected]
------------------------------
-------------------------------------------
Original Message:
Sent: 05-27-2025 08:40
From: James Moss
Subject: Cleaning Gravestones with D/2 Biological Solution

                     Dear Colleagues,
   
  I am a Cemetery Commissioner in my small Town (I am also a retired 
Conservator of Clocks). Members of my Committee have suggested using a 
commercial product called D2 to clean the gravestones of lichens and 
accumulated atmospheric "dirt". I've looked at D2's WEB site and their product 
SDS (mixture contains trisodium nitrilotriacetate and sodium metasilicate, 
anhydrous which are considered hazardous chemicals to humans). 
   
  Their WEB site [ https://www.d2bio.com/ <https://www.d2bio.com/> ] claims the 
following:
  

"National Parks Study Recommends D/2 for Government Headstone Cleaning" : 
Researchers studied five different cleaners on stones located in five different 
climates at locations across the United States. Microbiologists at Harvard 
University evaluated samples for regrowth of microorganisms including bacteria, 
fungi, and algae. D/2's quaternary ammonium solution came out on top! [Note: 
any mention of ammonia or its relations immediately causes my antennae to arise 
because it can cause Stress Corrosion Cracking of brass, a metal that 80% of 
clocks are made with]
  AND:
  The National Cemetery Administration now uses D/2. 
  "The NCA entered into an agreement with the National Center for Preservation 
Technology and Training, NPS, to evaluate marble cleaners in an effort to 
minimize damage to historic headstones. The 3-phase study began in 2004 and was 
completed in 2011. The best - practice recommendations resulted in NCA's 
determination to use the preferred cleaner, D/2 Biological Solution..." (Page 3)
  AND:
   
  "No Other Solution is more trusted by conservators" 
   
  Cleaning of Stone is not my specialty, I have not been trained to do stone 
treatments. 
   
  I know nothing about the effects of using the wrong chemical solutions or 
procedures on stone. All that I am aware of is that stone is porous and 
solutions can penetrate the stone and could cause long term degradation. I will 
attempt to contact a Conservator whose specialty is the cleaning of stone. In 
the meantime, I turn to you as a font of knowledge.....
   
  My first question to you is: 
  Is using this commercial solution harmful to the stones that are commonly 
used as cemetery markers such as slate, granite, and marble (aluminum and brass 
are also used but as far as I know, D2 is not used to clean these metals)?
   
  My second question is: 
  If D2 is not acceptable are there other safe methods that could be used by 
non-Conservators or Citizen Volunteers that would not cause short or long term 
harm to these objects?
   
  Your insights, help, and guidance would be most appreciated.
   
  Sincerely
   
  Jim Moss, 
  Horological Conservator, 
  AIC PA retired
   
      

4.From: Katherine Ridgway
 Posted: Friday May 30, 2025  12:02 PM
 Subject: RE: Cleaning Gravestones with D/2 Biological Solution
 Message:  
I would also like to hear other's opinion on all quaternary ammonium compounds 
(besides just D/2). If anyone has more up-to-date research, I would love to see 
it. The questions I have are:
 
 
 
What effect does it have on metals frequently associated with gravestones?
 
 
 
The main study having to do with government headstones helps me very little 
with many aspects of older cemeteries in my state. Government headstones are 
frequently replaced when damaged, and that is not what  I am usually advising 
on. The government headstones are also very uniform in material and other 
aspects, which is great for studies, but not helpful in the real world (hence 
my question about metals). 
 
 
 
There are also concerns in the health care industry about resistance to quats. 
Is that a concerns for gravestones? Will we eventually create biofilms that 
quats can't touch?
 
 
 
This is beyond all of the other health and safety and environmental concerns.
 
 
 
I would love to know peoples' thoughts.
 
 
 
Kate
 
 
 
 
     
 
 
  <https://www.facebook.com/VADHR/>   <https://www.instagram.com/vadhr_shpo/>   
<https://www.linkedin.com/company/vadhr/>   <https://twitter.com/VaDHR_SHPO>
   
Katherine Ridgway
 
State Archaeological Conservator
 
Department of Historic Resources
 
 
 
Email  [email protected] <[email protected]>
 
Phone  804-482-6442
 

 
 
 
2801 Kensington Ave, Richmond, VA 23221
 
www.dhr.virginia.gov <http://www.dhr.virginia.gov/>
     
 
 
 
 

-------------------------------------------
Original Message:
Sent: 5/29/2025 7:43:00 AM
From: James Moss
Subject: RE: Cleaning Gravestones with D/2 Biological Solution


Lorraine,


Nice to hear from You! Good thoughts indeed.


What you provided will be very useful when I present the information to the 
Commission: it will help them to understand a larger picture....and it is 
better coming from you than from me!


Jim


------------------------------
James Moss
Owner/Conservator
Boxborough
United States
------------------------------
-------------------------------------------
Original Message:
Sent: 05-29-2025 07:02
From: Lorraine Schnabel
Subject:  Cleaning Gravestones with D/2 Biological Solution


Jim,

Rather than directly addressing your question about D/2, I would pose the more 
fundamental question that confronts architectural conservators on a daily 
basis, which is should you clean at all? Are the stones being cleaned so the 
inscriptions can be recorded? Or is there some other compelling reason for 
cleaning other than to make the cemetery "look better?" Are you able to change 
the environment such that the soiling is unlikely to return (sometimes possible 
with buildings)? Giving volunteers something to do is not a compelling reason. 

Much of the "dirt" on grave markers is biological (a biofilm), and the 
quaternary ammonium compounds in commercial biological cleaners work to varying 
degrees to remove this type of soiling. The effects of cleaning can be 
dramatic, as numerous videos on YouTube will attest. However, the long-term 
effectiveness of such cleaning products is limited, especially if no concurrent 
changes are made to the environment of the object being cleaned. The soiling 
will return, sometimes rather quickly depending on the composition of the 
biofilm and the nature of the environment. Even if you are prepared to set up a 
long-term maintenance program to repeat the cleaning as the soiling inevitably 
returns, biofilms will adapt over time such that the cleaning chemical becomes 
less effective. Use of water repellents as a means of controlling the 
environment does not have a good track record, and there is plenty of 
literature that addresses concerns surrounding application of water repellents 
to masonry. 

Also, any amount of scrubbing amounts to a type of mechanical weathering that 
will immediately or eventually cause surface loss, depending on the type and 
state of deterioration of the marker. Lichen in particular can be highly 
resistant to removal on weathered stone surfaces without some amount of 
scrubbing.

If you want to take a positive action to preserved the cemetery, consider other 
steps. Most small cemeteries have no record of burials, so creating a database 
that includes all the information on the markers and photographing them is one 
valuable effort volunteers can make to preserve a cemetery. Inputting that 
information into a resource like Find a Grave is helpful to genealogical 
researchers. Creating a map of the cemetery (useful to develop a numbering 
system for the database), including elements of the landscape, would provide a 
means of locating the stones you have documented. Historical research to flesh 
out the database can help put a face on the history of the community the people 
in the cemetery were a part of. Properly supervised, volunteers can straighten 
markers that are leaning, and re-set markers that have toppled, but this effort 
needs to be led by someone with experience in lifting and moving things that 
are both heavy and fragile, and ideally a trained conservator
 if any sort of reassembly is needed.

Maintaining the cemetery grounds is critical to their preservation--volunteers 
who are willing to hand trim around graves and use push mowers prevents the use 
of string trimmers that damage the stone and zero turn or riding mowers used by 
most landscaping companies that can cause untold damage to markers.  Money 
available for cleaning chemicals could instead be used for tree-trimming, 
something that is often needed in older cemeteries to protect markers from 
being damaged by falling tree limbs, or for repair of walls and/or fencing.

I hope any of this information is of some use. 

Kind regards,


------------------------------
Lorraine Schnabel
Schnabel Conservation LLC
[email protected] <[email protected]>
------------------------------

Original Message:
Sent: 05-27-2025 08:40
From: James Moss
Subject: Cleaning Gravestones with D/2 Biological Solution

                     Dear Colleagues,
   
  I am a Cemetery Commissioner in my small Town (I am also a retired 
Conservator of Clocks). Members of my Committee have suggested using a 
commercial product called D2 to clean the gravestones of lichens and 
accumulated atmospheric "dirt". I've looked at D2's WEB site and their product 
SDS (mixture contains trisodium nitrilotriacetate and sodium metasilicate, 
anhydrous which are considered hazardous chemicals to humans). 
   
  Their WEB site [ https://www.d2bio.com/ <https://www.d2bio.com/> ] claims the 
following:
  

"National Parks Study Recommends D/2 for Government Headstone Cleaning" : 
Researchers studied five different cleaners on stones located in five different 
climates at locations across the United States. Microbiologists at Harvard 
University evaluated samples for regrowth of microorganisms including bacteria, 
fungi, and algae. D/2's quaternary ammonium solution came out on top! [Note: 
any mention of ammonia or its relations immediately causes my antennae to arise 
because it can cause Stress Corrosion Cracking of brass, a metal that 80% of 
clocks are made with]
  AND:
  The National Cemetery Administration now uses D/2. 
  "The NCA entered into an agreement with the National Center for Preservation 
Technology and Training, NPS, to evaluate marble cleaners in an effort to 
minimize damage to historic headstones. The 3-phase study began in 2004 and was 
completed in 2011. The best - practice recommendations resulted in NCA's 
determination to use the preferred cleaner, D/2 Biological Solution..." (Page 3)
  AND:
   
  "No Other Solution is more trusted by conservators" 
   
  Cleaning of Stone is not my specialty, I have not been trained to do stone 
treatments. 
   
  I know nothing about the effects of using the wrong chemical solutions or 
procedures on stone. All that I am aware of is that stone is porous and 
solutions can penetrate the stone and could cause long term degradation. I will 
attempt to contact a Conservator whose specialty is the cleaning of stone. In 
the meantime, I turn to you as a font of knowledge.....
   
  My first question to you is: 
  Is using this commercial solution harmful to the stones that are commonly 
used as cemetery markers such as slate, granite, and marble (aluminum and brass 
are also used but as far as I know, D2 is not used to clean these metals)?
   
  My second question is: 
  If D2 is not acceptable are there other safe methods that could be used by 
non-Conservators or Citizen Volunteers that would not cause short or long term 
harm to these objects?
   
  Your insights, help, and guidance would be most appreciated.
   
  Sincerely
   
  Jim Moss, 
  Horological Conservator, 
  AIC PA retired
   
      

5.From: Howard Wellman
 Posted: Friday May 30, 2025  1:23 PM
 Subject: RE: Cleaning Gravestones with D/2 Biological Solution
 Message: 
Jim,


There have been a lot of great responses to your original query, but I realized 
that some of the issues you raised may not have been addressed.  So I took the 
time to go review the SDS on the D/2 website and also dig out my notes from my 
personal discussions with the developers and manufacturer of D/2.


1) I cannot find mention of the two chemicals you cite (trisodium 
nitrilotriacetate and sodium metasilicate, anhydrous) in the SDS.  Can you tell 
me where you saw those?  


2) A couple years ago I called Tony Kinnari at D/2 and asked about the ammonia 
content in a quaternary ammonium compound, specifically because I was concerned 
about reaction with bronze plaques and hardware on gravestones.  I was told 
that the chemistry of "ammonium" in this case refers to a nitrogen with three 
branching functional groups, not to the specific molecule NH3 of ammonia, which 
is not present in D/2.  So this should ease fears about its effect on copper 
alloys.  Although as you say in your message, no one is likely to use D/2 on a 
bronze object deliberately, since bronze doesn't grow that kind of biological 
community.


3) I also asked about the presence of free chloride ions (many quats are 
ammonium chloride salts) (and forgive me if I do make incorrect chemical names 
here), based on my worries about the effects of chloride on iron alloys used in 
gravestone hardware.  They pointed out (and see the SDS) that in the D/2 
product, the quats are 2% of the total mixture, therefore, free chloride ion is 
likewise 2%, which is far less than most other commercial cleaning products, 
especially bleaches.  You might get that much free chloride ion wicking up 
through the gravestone from groundwater?  Which explains why so many historic 
gravestones already suffer from corroding iron pins prior to the use of modern 
cleaners?


4) Jason Church at NCPTT who did many of those tests on D/2 did not find any 
damage to stone from recrystallization of the chemical, if it even occurred.


5) Regarding human safety, I admit that I find the odor of D/2 harsh, but don't 
forget that hospitals and food service industries have been using similar quats 
for years as surface sanitizers, and especially during the pandemic.  Maybe 
there are subtle differences between those quats and D/2 that I'm not aware of, 
and I regret that I haven't read any specific publications addressing those 
questions.


I hope that this contributes to the conversation.


Sincerely,


Howard


------------------------------
Howard Wellman 
Halethorpe MD
------------------------------
-------------------------------------------
Original Message:
Sent: 05-27-2025 08:40
From: James Moss
Subject: Cleaning Gravestones with D/2 Biological Solution

                     Dear Colleagues,
   
  I am a Cemetery Commissioner in my small Town (I am also a retired 
Conservator of Clocks). Members of my Committee have suggested using a 
commercial product called D2 to clean the gravestones of lichens and 
accumulated atmospheric "dirt". I've looked at D2's WEB site and their product 
SDS (mixture contains trisodium nitrilotriacetate and sodium metasilicate, 
anhydrous which are considered hazardous chemicals to humans). 
   
  Their WEB site [ https://www.d2bio.com/ <https://www.d2bio.com/> ] claims the 
following:
  

"National Parks Study Recommends D/2 for Government Headstone Cleaning" : 
Researchers studied five different cleaners on stones located in five different 
climates at locations across the United States. Microbiologists at Harvard 
University evaluated samples for regrowth of microorganisms including bacteria, 
fungi, and algae. D/2's quaternary ammonium solution came out on top! [Note: 
any mention of ammonia or its relations immediately causes my antennae to arise 
because it can cause Stress Corrosion Cracking of brass, a metal that 80% of 
clocks are made with]
  AND:
  The National Cemetery Administration now uses D/2. 
  "The NCA entered into an agreement with the National Center for Preservation 
Technology and Training, NPS, to evaluate marble cleaners in an effort to 
minimize damage to historic headstones. The 3-phase study began in 2004 and was 
completed in 2011. The best - practice recommendations resulted in NCA's 
determination to use the preferred cleaner, D/2 Biological Solution..." (Page 3)
  AND:
   
  "No Other Solution is more trusted by conservators" 
   
  Cleaning of Stone is not my specialty, I have not been trained to do stone 
treatments. 
   
  I know nothing about the effects of using the wrong chemical solutions or 
procedures on stone. All that I am aware of is that stone is porous and 
solutions can penetrate the stone and could cause long term degradation. I will 
attempt to contact a Conservator whose specialty is the cleaning of stone. In 
the meantime, I turn to you as a font of knowledge.....
   
  My first question to you is: 
  Is using this commercial solution harmful to the stones that are commonly 
used as cemetery markers such as slate, granite, and marble (aluminum and brass 
are also used but as far as I know, D2 is not used to clean these metals)?
   
  My second question is: 
  If D2 is not acceptable are there other safe methods that could be used by 
non-Conservators or Citizen Volunteers that would not cause short or long term 
harm to these objects?
   
  Your insights, help, and guidance would be most appreciated.
   
  Sincerely
   
  Jim Moss, 
  Horological Conservator, 
  AIC PA retired
   
      

6.From: Leah Bright
 Posted: Friday May 30, 2025  1:23 PM
 Subject: There's still time to register for APOYOnline's 5th Regional 
Conference "Sustainable Connections for Cultural Heritage"
 Message: There's still time to register for APOYOnline's 5th Regional 
Conference!

APOYOnline 5th Regional Conference: Sustainable Connections for Cultural 
Heritage
Panama City, Panama & Virtually
June 30 to July 4, 2025

APOYOnline - the Association for Heritage Preservation of the Americas, Inc., 
is proud to host our upcoming 5th Regional Conference & Workshops from June 
30th to July 4th, 2025, with the theme "Sustainable Connections for Cultural 
Heritage." The in-person event will take place at the Ciudad del Saber 
Conference Center in beautiful and fascinating Panama City, Panama. The 
conference will also be presented online and is being co-organized with the 
Museo del Canal and other regional institutions in Panama.

Nearly 170 authors from 24 countries will present over 70 papers and 50 posters 
during the event concerning the following topics:



Climate Change & Collections at Risk



Community Engagement & Connections



Innovation & Trends



Education & Training


Notably, over 60% of participants in the conference are students and emerging 
professionals attending an APOYOnline event for the first time. Thanks to our 
exceedingly generous sponsors, APOYOnline is providing stipends to each author 
to support their attendance both in person and online.

See APOYOnline's website <https://apoyonline.org/> for more information and to 
register for the conference. See you soon in Panama and online! 

--
Leah A. Bright (she/her/ella) 
Board Secretary
APOYOnline - Association for Heritage Preservation of the Americas
[email protected]


------------------------------
Leah A. Bright  she/her
Objects Conservator
Smithsonian American Art Museum and Renwick Gallery  Lunder Conservation Center
(202) 633-5804  
[email protected]
------------------------------




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