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 Kirstine, W., Galbally, I. E., Ye, Y., and Hooper, M.A. (1998).
 Emissions of volatile organic compounds (primarily oxygenated
 species) from pasture.  Journal of Geophysical Research, 103
 (D9): 10605-10619.

 The volatile organic compound (VOC) emissions from pasture at a
 site in southeastern Victoria, Australia, were monitored over a 2
 year period using a static chamber technique.  Fluxes up to 23,000
 mg(C) m<sup>-2</sup> h<sup>-1</sup> were detected, with the higher
 fluxes originating from clover rather than from grass species.  Gas
 chromatographic analyses indicated that emissions from both grass
 and clover were high in oxygenated hydrocarbons including methanol,
 ethanol, propanone, butanone, and ethanal, and extremely low in
 isoprene and monoterpenes.  In the case of clover, butanone made up
 45-50% of the total emissions.  When grass and clover were freshly
 mown, there were significantly enhanced emissions of VOCs.  These
 enhanced emissions included both those oxygenates emitted from
 uncut pasture and also C<sub>6</sub>-oxygenates, including
 (Z)-3-hexenal, (E)-2-hexenal, (2)-2-hexen-1-ol, (Z)-3-hexen-1-ol,
 and (Z)-3-hexenyl acetate.  Emissions from the undisturbed pasture
 increased markedly with temperature and the intensity of solar
 radiation, peaking at midday and ceasing at night.  The fluxes,
 when normalized to a temperature of 30&#176; C and a light
 intensity of 1000 m E m<sup>-2</sup> s<sup>-1</sup> were, for grass
 and clover respectively, about one eighth and two fifths of the
 equivalent fluxes reported to occur from U.S. woodlands.  The
 annual integrated emission from the pasture was approximately 1.9
 g(C) m<sup>-2</sup> or 1.3 mg(C) g<sup>-1</sup> (dry matter).  The
 large transient fluxes that occurred following physical damaging of
 the pasture, when integrated over time, could be of the same order
 as those emissions that were observed from undisturbed pasture.
 In the case of methanol, and perhaps ethanol, the emissions from
 grasslands may be significant global sources of these gases.
 (Author abstract).





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