-Caveat Lector-

"Environmentally friendly" explosives get ready for ignition

<http://www.newscientist.com/news/news.jsp?id=ns99991244>

05  September  01
Damian Carrington, Glasgow

The advent of environmentally friendly explosives has moved a step closer,
with German scientists solving the problem of water absorption in one
promising compound - the moisture literally turns the compound into a damp
squib.
"It may sound strange that military are concerned about health and safety,"
says Thomas Klapotke, at the University of Munich. "But 99.9 percent of
missile launches and explosions take place in training, over your own
territory and involving your own personnel."
Conventional explosives and missile propellants are packed with metals and
halogens, which can be harmful before and after combustion. Even guns can
produce smogs of lead compounds in the indoor shooting ranges now used by
many police forces, because lead azide is used as the initiator.
"I would not call them environmentally friendly, but environmentally
compatible," Klapotke told New Scientist. But replacing conventional
explosives with compounds containing only nitrogen, carbon, hydrogen and
oxygen means the only combustion products are N2, water and methane - "hot
air", says Klapotke.
                    Rained off
Klaptoke has been working with the highly explosive compound hydrozinium
azide (N5H5) but the synthesis process used meant it was highly
hydroscopic. The water attracted completely defuses the explosive properties.
However, Klapotke found that by crystallising hydrozinium azide directly
from water-free hydrazine, the hydroscopic property was removed. The work
has just been published in the journal Propulsion, Explosives and Pyrotechnics.
Hydrozinium azide is particularly promising because its combustion products
are N2 and H2 alone. The lightness of these gases means that the detonation
velocity is especially high and when the H2 burns to produce water just
milliseconds later, a second powerful burst of energy is released.
                    Big bang
The new generation of explosives need not only be greener, they can also be
more powerful. Klapotke has found that diazyltetrozolate, which is 90
percent nitrogen by weight, is 25 percent more powerful than HMX, the most
powerful explosive currently in use.
A number of groups in countries belonging to the NATO military alliance are
investigating green explosives, but are taking different approaches. The
German team is looking at compounds that store their energy in single
nitrogen to nitrogen bonds. When detonated, the atoms form highly stable
triple nitrogen to nitrogen bonds, releasing energy.
In contrast, US teams are testing materials in which the energy is stored
as molecular strain in twisted chains or rings of atoms.
The key difficulty that remains to be overcome is cost. Currently green
explosives are 100 times more expensive to produce than conventional ones.
Klapotke believes that even at best the new generation materials will be
double or triple the price, but says that the military is highly committed
to developing less environmentally harmful options. "If your new explosive
has metals or halogens in, its not even worth putting on the drawing
board," he says.
Klapotke presented his research at the British Association's Festival of
Science in Glasgow.

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