-Caveat Lector-

Source:   University Of Pennsylvania (http://www.upenn.edu/)

Penn Engineers Develop Fuel Cell That Uses Liquid Diesel, The First Such
Device To Run On A Widely Available Fuel

PHILADELPHIA - Chemical engineers at the University of Pennsylvania have
developed a prototype fuel cell that's the first to run on a readily
available liquid fuel source, in this case ordinary diesel fuel. The work
nudges fuel cells closer to viability, offering the promise of compact,
portable power sources that offer much more bang for the buck than
combustion engines or existing batteries. Scientists, corporations and the
military are all interested in fuel cells, which are far more efficient and
less polluting than other energy sources. Work to develop commercial fuel
cells, however, has been hindered by the limited fuel sources on which they
have been known to run.
"There used to be a saying that you could run a fuel cell on any fuel as
long as it's hydrogen," said Raymond J. Gorte, professor of chemical
engineering at Penn and the lead author of a Journal of the Electrochemical
Society paper reporting the finding.

Gorte and colleague John M. Vohs, professor and chair of chemical
engineering at Penn, shook the fuel cell world in March 2000 with the
publication of a Nature paper in which they reported developing a fuel cell
that could run on butane, the first fuel cell to operate on a fuel other
than hydrogen. With the development of a fuel cell that runs directly on
liquid diesel of the type sold at gas stations, the team has sidestepped the
thorny problem of "reforming" fuels to hydrogen to run fuel cells.

"In our earlier work, we were unable to feed liquid diesel to the fuel cell
because we did not have a means for vaporizing fuels that have a low vapor
pressure at room temperature," Gorte said. "This paper demonstrated that we
could feed these liquids to a fuel cell using a method analogous to a fuel
injector in an internal combustion engine and still get stable operation of
the fuel cell."

Much past research with fuel cells has focused on the messy question of how
best to process, or "reform," available hydrocarbon fuels such as diesel
into pure hydrogen, an expensive and inefficient proposition. The Penn fuel
cell is the first to run directly on hydrocarbons, without requiring
complicated reforming into hydrogen either within the device itself or at
specialized filling stations. Generating electric power through controlled
electrochemical reactions rather than combustion, its only emissions are
water, carbon dioxide and heat.

Smaller than a penny, the prototype fuel cell developed by Gorte, Vohs,
graduate student Hyuk Kim and postdoctoral researcher Seungdoo Park
operates
in a furnace set at 700 degrees Celsius. A commercial, self-contained fuel
cell would ideally generate that heat itself using the fuel placed in it.

Although unlikely to replace household batteries for small appliances and
portable electronics, researchers have suggested that fuel cells might be
appropriate for powering cars and laptop computers.

"We are excited by the progress that Professor Gorte and his colleagues are
making in the area of direct oxidation of hydrocarbon fuels using solid
oxide fuel cells," said David Bauer, team leader for the Solid Oxide Fuel
Cell project at the Ford Research Laboratory in Dearborn, Mich. "The ability
to utilize conventional fuels with little or no reforming is particularly
important in transportation applications where fuel storage and system
packaging are such critical issues."

Fuel cells could also make possible electric generators that operate on
propane or butane. Gorte's team is interested in developing a relatively
small, five-kilowatt fuel cell. Such a unit, placed in a home's basement,
could be used to generate electricity from natural gas, using the excess
energy to heat the home or its hot water.

"It's much more efficient to produce energy on-site than it is to make it
many miles away," Gorte said.

The U.S. military regards fuel cells as a possible source of portable "palm
power" for soldiers carrying electronic devices. Together with Honeywell,
Penn researchers have recently been awarded $1.8 million by the U.S. Army
and the Defense Advanced Research Projects Administration to develop a
coffee-can-sized fuel cell capable of generating power equivalent to 50
D-cell batteries. The military is particularly interested in diesel-run fuel
cells because diesel's low vapor pressure makes it less explosive and
therefore safer; the Penn fuel cell also runs on the hydrocarbons toluene
and n-decane.

DARPA has indicated to the team that it would like fuel cell technology to
find civilian applications. "We believe this is very doable and that this
technology should be very easily modifiable for many applications," Gorte
said.


Gorte, Vohs, Kim and Park's work with solid oxide fuel cells was funded by
the Office of Naval Research and published in the July issue of JECS.

--

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