I think it's either/or, not both. The effect is similar, with tone curve boosing saturation less than base curve. https://www.darktable.org/usermanual/ch03s04.html.php 'If you intend to take full manual control of the tonal values with the tone curve module or the zone system module (see Section 3.4.2.3, “Tone curve” and Section 3.4.2.4, “Zone system”) it may be easier to leave the image in linear RGB. Disable the base curve module in this case.'
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