I too have experienced this problem. For me, the $PATH was the cause. When
I su in Buster, my $PATH does not contain /sbin and /usr/sbin. debootstrap
is in /usr/sbin/ and hence could not be found when running live-build when
su'ing in the terminal. It worked perfectly when I exported /usr/sbin and
/sbin into my $PATH. Live-build also worked perfectly when I su -l in the
terminal. Hope this helps. It does not appear to be a live-build problem,
but a $PATH problem.

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