Sorry for writing this here, but someone might find this useful anyway. The spooler gets files from MS-Word. If MS-Word prints the documents with the setting. PrintOnBackGround (Found in Extra - Options - Printing) then the spooler deems the prints not important enough and decides (or the driver) which is the order of printing. When the specific option is set to BackGroundPrinting := False; Every document is printed immediately.
Sorry for disturbing you all.
