This isn't likely to be a gnome-session issue. Could you attach the
desktop file created in ~/.config/xdg/autostart when you add Nautilus to
Startup Applications. Nautilus already runs at startup anyway, so what
are you trying to achieve by adding it again?
** Changed in: gnome-session (Ubuntu)
Status: Triaged => Incomplete
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Nautilus won't run from Sessions or Startup Applications
https://bugs.launchpad.net/bugs/346331
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