Think it's not about gnome, but about pulseaudio/alsa.
I have the same problem, you can try first workaround from this guide.

https://wiki.ubuntu.com/DebuggingSoundProblems/KarmicCaveats#Volume%20range%20anomalies

After this my volume control works as expected.

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volume control app operates over ~25% of range
https://bugs.launchpad.net/bugs/508733
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