Confirmed with sr_RS. Solution is to open alacarte with LANG=en_US
alacarte. Output is
LANG=en_US alacarte
(process:1638): Gtk-WARNING **: Locale not supported by C library.
Using the fallback 'C' locale.
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cannot edit gnome menus (alacarte)
https://bugs.launchpad.net/bugs/422899
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