You have been subscribed to a public bug:
Basically sessions do not get persisted hence any changes are lost after reboot.
Example:
I've added Beryl Manager, Gaim and Firestarter to:
System -> Preferences -> Sessions [Startup Programs]
so I don't have to launch them manually every time I log into the
system.
In the [Session Options] Tab, I've pressed the button labeled "Save the
current session", and also the check box that reads "Automatically save
changes to session" is already selected.
Now if I reboot the system or log off, I've lost those changes.
** Affects: gnome-session (Ubuntu)
Importance: Undecided
Status: Needs Info
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Session does not persist after reboot
https://bugs.launchpad.net/bugs/118495
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