The same happens on Ubuntu Gnome versions. It looks like apparmour problem. 
I did next steps to make it work:

ln -s /etc/apparmor.d/usr.lib.libreoffice.program.oosplash 
/etc/apparmor.d/disable/
apparmor_parser -R /etc/apparmor.d/usr.lib.libreoffice.program.oosplash 

ln -s /etc/apparmor.d/usr.lib.libreoffice.program.soffice.bin 
/etc/apparmor.d/disable/
apparmor_parser -R /etc/apparmor.d/usr.lib.libreoffice.program.soffice.bin 

ln -s /etc/apparmor.d/usr.lib.libreoffice.program.senddoc 
/etc/apparmor.d/disable/
apparmor_parser -R /etc/apparmor.d/usr.lib.libreoffice.program.senddoc 

And after that I had to replace sensible-lomua with thunderbird inside
LO Tools -> Settings -> Internet -> E-mail client.

I don't know why sensbile-lomua does not exist anymore and nothing else
works. Even if I put xdg-email or just thunderbird. Without apparmor
changes it does nothing.

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You received this bug notification because you are a member of Desktop
Packages, which is subscribed to libreoffice in Ubuntu.
https://bugs.launchpad.net/bugs/1899667

Title:
  LO can't send email, probably an apparmour problem

Status in kmail package in Ubuntu:
  Confirmed
Status in libreoffice package in Ubuntu:
  Confirmed

Bug description:
  LO can't send email:

  LibreOffice was unable to find a working email configuration.

  I'm pretty sure this is an apparmour profile problem since LO seems to
  want RW perms on something and AA seems not to want to give it. There
  lies the full extent on mu debugging expertise in this area.

  ProblemType: Bug
  DistroRelease: Ubuntu 20.04
  Package: ubuntu-release-upgrader-core 1:20.04.25
  ProcVersionSignature: Ubuntu 5.4.0-48.52-generic 5.4.60
  Uname: Linux 5.4.0-48-generic x86_64
  NonfreeKernelModules: nvidia_modeset nvidia
  ApportVersion: 2.20.11-0ubuntu27.9
  Architecture: amd64
  CasperMD5CheckResult: skip
  CrashDB: ubuntu
  CurrentDesktop: KDE
  Date: Tue Oct 13 17:01:43 2020
  InstallationDate: Installed on 2017-03-26 (1297 days ago)
  InstallationMedia: Kubuntu 16.10 "Yakkety Yak" - Release amd64 (20161012.1)
  PackageArchitecture: all
  SourcePackage: ubuntu-release-upgrader
  Symptom: release-upgrade
  UpgradeStatus: Upgraded to focal on 2020-10-08 (4 days ago)
  VarLogDistupgradeXorgFixuplog:
   INFO:root:/usr/bin/do-release-upgrade running
   INFO:root:No xorg.conf, exiting

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