Try this, and let us know whether this resolves the problem:
sudo apt install xdg-desktop-portal-gnome
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Packages, which is subscribed to chromium-browser in Ubuntu.
https://bugs.launchpad.net/bugs/1970148
Title:
Brave & Chrome browsers freezes on download and print to pdf
Status in chromium-browser package in Ubuntu:
Incomplete
Bug description:
Whenever any file is downloaded, the browser will freeze.
Similarly, the browser will freeze when a page is printed to pdf.
To manage notifications about this bug go to:
https://bugs.launchpad.net/ubuntu/+source/chromium-browser/+bug/1970148/+subscriptions
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