org.apache.poi.openxml4j.opc.PackageRelationshipTypes has the following
remark:

/**
 * Core properties relationship type.
     *
     *  <p>
     *  The standard specifies a source relations ship for the Core File
Properties part as follows:
     *  <code>
http://schemas.openxmlformats.org/officedocument/2006/relationships/metadata/core-properties
.</code>
     *  </p>
     *  <p>
     *   Office uses the following source relationship for the Core File
Properties part:
     *   <code>
http://schemas.openxmlformats.org/package/2006/relationships/metadata/core-properties
.</code>
     * </p>
     * See 2.1.33 Part 1 Section 15.2.11.1, Core File Properties Part in
[MS-OE376].pdf
 */

This may have been true in an older version of ECMA-376 but the latest
edition (dated December 2012) specifies the same schema as the Office one.

ECMA-376 Part 2 Annex F Table F-1 lists the namespace URI as "
http://schemas.openxmlformats.org/package/2006/metadata/core-properties";.

Are there any known XLSX exporters that use the non-office schema?
 Unfortunately I didn't find a comment in the source about it.

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