did you try to use this operation
http://explorer.nuxeo.org/nuxeo/site/distribution/current/viewOperation/Document.Update

with this syntax for the parameter value:

 dc:subjects=arts/architecture,arts/cinema

Also, could you use answers.nuxeo.com ?  

Finally, if you are very interested in php automation
client, we are looking for contributors on it, so you are
very welcome for improving it :)
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