Hello Louie: 

I can offer up some insight into your question on insecticide use around 1980. 
At that time, many of the organochlorines (e.g., DDT, etc.) had been 
restricted, and organophosphorous (e.g., diazinon, etc.) and carbamate (e.g., 
carbofuran, etc.) insecticides dominated. Another group that had been in 
development from the 1960s was the synthetic pyrethroids. These were derived 
from pyrethrum, a compound with known insecticidal properties found in East 
African chrysanthemums. The 1st generation synthetic pyrethroids had low 
mammalian toxicity but were very sensitive to light, so they had very short 
persistence in daylight. By the mid-1970s, chemists had come up with 2nd 
generation synthetic pyrethroids (e.g., permethrin, cypermethrin, deltamethrin, 
etc.). These 2nd generation compounds were much more resistant to degradation 
by light and air, thus making them more suitable for agriculture. However, by 
tweaking their chemistry in this way, they substantially increased their 
mammalian toxicity. So, by 1980, the 2nd generation synthetic pyrethroids began 
making their way in number to the agricultural insecticide markets. So, this 
may help explain the decline in Mexican bean beetles you mentioned in your 
email - or at least it could be one factor in their decline. 


One other thing to consider about synthetic pyrethroids on the market - they 
usually have a compound called piperonyl butoxide (PB) added to them, which is 
a synergist. This causes the pesticide to be more effective because the PB 
inhibits the detoxifying enzymes of organisms which would be used by the 
organisms to deal with the synthetic pyrethroid insecticide. 


You mentioned mode of action - synthetic pyrethroids act by keeping Na+ 
channels open in neurons, so organisms become paralyzed (muscles all fatigue) 
and eventually die. This is pretty much the same mode of action seen with the 
organochlorine insecticides in wide use prior to 1973. 


Hope this helps! 


Regards, 


Steve 
Steve Sheffield, Ph.D. 
Department of Natural Sciences 
Bowie State University 
Bowie, MD 20715 
and 
College of Natural Resources and Environment 
Virginia Tech 
National Capital Region - Northern Virginia Center 
Falls Church, VA 22043 
[email protected] 

----- Original Message -----
From: "Louis Nottingham" <[email protected]> 
To: [email protected] 
Sent: Sunday, March 3, 2013 1:04:47 PM 
Subject: [ECOLOG-L] Question about insecticides 

I am interested to know if there were any significant changes and/or 
advancements in insecticide use that began around 1980 (new chemical, shift 
to a different mode of action, etc.). 

I am trying to formulate a hypothesis regarding what caused a sharp 
decline in Mexican bean beetle in soy and snap beans that occurred around 
1980 (an observation that has been corroborated by numerous extension 
agents). It is possible that the decline involved climate change, but 
according to surveys i've conducted, it still is a pretty severe issue in 
the organic farming community. So I am guessing that we must have developed 
some sort of chemical, chemical treatment method, or something along those 
lines that was very successful for controlling the beetle in a conventional 
setting. 

Any thoughts? Good references? (I do not know much about insecticide use, 
so feel free to provide obvious information!) 

Louie Nottingham 
Virginia Tech Masters Candidate 
216(A) Price Hall (0319) 
Virginia Tech 
Blacksburg VA, 24061 

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