Looking at the header of your mail (`t' in gnus :), you'll see this
line:

List-Unsubscribe: <https://lists.gnu.org/mailman/options/emacs-orgmode>, 
<mailto:emacs-orgmode-requ...@gnu.org?subject=unsubscribe>

So, did you try to send an email to emacs-orgmode-requ...@gnu.org
with the a subject "unsubscribe" ?

hth
Memnon


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