On Friday 20 November 2009, Andy Pugh wrote:
>2009/11/20 Gene Heskett <gene.hesk...@gmail.com>:
>> A cube of dry ice sitting on
>> it would help, but would raise the available oxygen too.
>
>I am fairly sure it would displace the oxygen (being heavier) and so
>would both cool and reduce oxide formation.

That would depend on how easy it would be to obtain some oxygen from the co2 
vapors.  How active is carbon dioxide compared to say sulfur dioxide?  Sulfur 
dioxide is a very unstable gas, but its chemical reaction is the opposite as 
it will grab, by force, an oxygen molecule from any available src in its 
quest to convert itself to sulfur tri-oxide, which as some of us know it just 
another name for sulfuric acid.  This is why a leaking so2 refrigerant system 
(commonly used in household refrigerators back in the late 30 and mid-40's) 
is so deadly, the gas will steal the oxygen from the moisture in your lungs 
to make sulfuric acid and _that_ burns your lungs out.

 In the gas fired camper fridges, that is also the destruction mechanism for 
those as even one molecule of water sealed into that system will, over time, 
generate enough sulfuric acid to eat a hole in a thin spot someplace.  I 
don't believe you will ever see a 'Dometic" made unit that will ever have 
more than a 5 year warranty on its no moving parts refrigeration system for 
exactly that reason.  And if its gas fired, it IS a Dometic inside the brand 
name labels & has been so since the 1950's after Servel disappeared.  Today I 
think 12 volt versions of the little bitty fridges like wally sells for a bit 
over a hundred dollar bill have replaced those gas fired ones in 100% of the 
new weekend campers.  I have one in the basement that I carry with me when 
I'm going to be on the job someplace for more than 3 or 4 days. But it runs 
on wall power.

As for how active the carbon dioxide from the dry ice is, can it be broken 
down to supply the o in its o2?  I am not _that_ much of a chemist, hence the 
question. :(

 >You might have hit on a cunning plan, and it would look cool too.

I agree, but the expense of keeping one supplied with dry ice would also have 
to be a factor.  Locally, I believe its special order and several dollars a 
pound, weight measured at their end of the shipping of course. ;)

-- 
Cheers, Gene
"There are four boxes to be used in defense of liberty:
 soap, ballot, jury, and ammo. Please use in that order."
-Ed Howdershelt (Author)
The NRA is offering FREE Associate memberships to anyone who wants them.
<https://www.nrahq.org/nrabonus/accept-membership.asp>

There's no saint like a reformed sinner.

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