Hi,

Dave is working on the freezer to make concentrated
HTP out of lower-grade one, AFAIK. The logic, I
assume, according to
<http://www.h2o2.com/intro/properties/pic11a.gif>, is
the following: if you have a 30% (or some other lower
grade) HTP, and start cooling it, first the water
becomes ice, and only then the peroxide itself
freezes. So, at the intermediate state you can remove
the liquid, which will represent the higher grade of
HTP. If you have peroxide stronger than, say, 65%, the
peroxide will freeze first, so you'll get the ice of
strong peroxide, which you can then melt to get HTP.

The freezing is preferrable to sparging in that it
doesn't encourage you to heat the peroxide to speed up
the process; heating is more dangerous than freezing.
On the other hand, you have to reach rather low
temperatures, like -60F, to make an ice for certain
concentrations. An ordinary freezer, AFAIK, can't
provide you with such temperature; you're better off
with dry ice, but it may have its drawbacks with
obtaining, storing, moving, handling etc.

Is it possible to use liquid air, or LN2, to reach low
temperatures for HTP concentrating by freezing? Or is
there some other severe problems on this path?

Alex


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