soon. ;)

keskiviikko, 16. tammikuuta 2013 Kent Barnes <[email protected]>
kirjoitti:
> Okay, that worked. Great article....Holy s____t  when will someone start
> building them?
>
>
> -----Original Message-----
> From: [email protected] [mailto:[email protected]] On
Behalf
> Of robert winfield
> Sent: Wednesday, January 16, 2013 9:44 AM
> To: Electric Vehicle Discussion List
> Subject: Re: [EVDL] Stanford researchers develop sulfur cathode,giving
> Li-Ion 5 times higher energy density
>
>
http://spectrum.ieee.org/nanoclast/semiconductors/nanotechnology/nanoparticl
> e-enables-world-record-for-energy-storage-in-batteries
>
> Nanoparticle Enables World Record for Energy Storage in Batteries POSTED
BY:
> Dexter Johnson / Wed, January 09, 2013
>
> Share on printShare on emailShare on facebookShare on twitterShare on
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>
>
>
>
>
> With just one week under our belts in this New Year, we already have some
> world-record news in relation to lithium-ion (Li-ion) batteries and
> nanoparticles. Researchers at Stanford University and the SLAC National
> Accelerator Laboratory have developed a Li-ion battery in which its sulfur
> cathode was capable of storing five times more energy than is possible
with
> today’s commercially available batteries.
> The research—not surprisingly—was led by Stanford’s Yi Cui. What may be
> somewhat surprising is that Cui has focused his attention in this research
> on the cathode rather than the anode of the battery. Much of Cui’s most
> recent work has been on improving the anodes of Li-ion batteries through
the
> use of nanostructured silicon. In this latest research, he has not only
> shifted his attention to the cathode, but also developed an entirely new
> material to do it.
> The new material, which is described in the Jan. 8 edition of Nature
> Communications (“Sulphur–TiO2 yolk–shell nanoarchitecture with internal
void
> space for long-cycle lithium–sulphur batteries”), is a nanoparticle that
is
> made up of an inner core of sulfur surrounded by an outer layer of porous
> titanium-oxide. The nanoparticles architecture resembles that of the yolk
> and shell of an egg.
>
> This nanoparticle’s new architecture has broken down an obstacle to using
> sulfur in the cathode of Li-ion batteries that has persisted for around 20
> years.
> While it has been known that sulfur could store more lithium ions than
other
> cathode materials, the combination of sulfur atoms with lithium ions
> resulted in a compound—though necessary for the cathode to operate—that
kept
> dissolving and limited the storage capacity of the battery. Also, when the
> lithium ions went into the cathode, it would expand the size of the
cathode
> by 80 percent. Attempts to employ protective coatings to correct the first
> problem of the compound dissolving just resulted in them cracking as soon
> the lithium ions expanded the cathode.
> In the new architecture that Cui has developed, there is space between the
> sulfur and the hard—but porous—titanium oxide. What this means is that the
> sulfur-lithium intermediate compound does not dissolve because it is
> protected by hard outer surface of the nanoparticle and the sulfur inside
> has enough room to expand in the space between the core and the outer
shell.
> “It basically worked the first time we tried it,” Cui says in a press
> release. “The sulfur cathode stored up to five times more energy per
sulfur
> weight than today’s commercial materials."
> “After 1,000 charge/discharge cycles, our yolk-shell sulfur cathode had
> retained about 70 percent of its energy-storage capacity. This is the
> highest performing sulfur cathode in the world, as far as we know,” he
said.
> “Even without optimizing the design, this cathode cycle life is already on
> par with commercial performance. This is a very important achievement for
> the future of rechargeable batteries.”
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