Who at A123 told you that? Do they have test data of holding a cell at 3.45V for momths or years and no issues? Did they compare that with holding the cell at 3.40V or 3.38V? What, really, is the energy storage improvement by using the higher voltage assuming no adverse effects?
If I were in your position I wouldn't buy that. I'd do my own testing. I'd put a cell on at the 3.45V in a constant temperature environment and let it sit at that terminal voltage for a few hours and then measure any temperature difference between the cell and ambient. If the cell is warmer then it is being overcharged. Also, carefully measure the current going into the cell. If it is above 0µA it is being over charged. Do the same tests at 3.40V and 3.38V and compare results. If you capacity test the cells after being held at the different float voltages I'm sure you will find that there is a minuscule difference in energy storage. Furthermore, given that the NASA research summary I read a couple of years ago found that the calendar life of all Li based rechargeable batteries was shortened when left at 100% SOC as compared to a lower SOC, do you really need the cells at 100%+ all the time? Whatever you do please report your results. David D. Nelson http://evalbum.com/1328 http://www.levforum.com Sent from my Nokia Lumia 920 Windows Phone 8 From: Mark Hanson Sent: 2/19/2013 5:37 To: [email protected] Subject: [EVDL] LiFePO4 float charging Hi Folk's,A123 told me to float charge their D size cells to 3.45V when I was using them in a float charge UPS application.Best Regards,markwww.REEVA.info Message: 9 Date: Thu, 14 Feb 2013 22:33:53 -0800 From: "Cor van de Water" <[email protected]> To: "Electric Vehicle Discussion List" <[email protected]>, "Electric Vehicle Discussion List" <[email protected]> Subject: Re: [EVDL] 12V LiFePO4 batteries Message-ID: <[email protected]> Content-Type: text/plain; charset="iso-8859-1" Since the cells might not be perfectly balanced, I would expect that when one cell dips to 2V, you can expect the others still to be around 3V, so I guess that it would be prudent to disconnect when the voltage dips to 11V (3x3+2) BTW, I did not suggest to float-charge the cells at 3.45V indefinitely, since no car is running 24/7. Typically a car is used a short period, sometimes a few hours, and then shut down, from which moment the battery is slowly discharged until the car has been started again. I believe the highest current in a (ICE) car is starting cold. That can run close to 1000A peak. Because AFAIK most alternators are in the 100A region, but it is certainly good to check for max charging current and adjust for it. NOTE that the net charging current is the difference between the alternator's generated current and the consumption of the car. Regards, Cor van de Water Chief Scientist Proxim Wireless Corporation http://www.proxim.com Email: [email protected] Private: http://www.cvandewater.com Skype: cor_van_de_water XoIP: +31877841130 Tel: +1 408 383 7626 Tel: +91 (040)23117400 x203 -------------- next part -------------- An HTML attachment was scrubbed... URL: <http://lists.evdl.org/private.cgi/ev-evdl.org/attachments/20130219/cbf00a48/attachment.htm> _______________________________________________ UNSUBSCRIBE: http://www.evdl.org/help/index.html#usub http://lists.evdl.org/listinfo.cgi/ev-evdl.org For EV drag racing discussion, please use NEDRA (http://groups.yahoo.com/group/NEDRA) _______________________________________________ UNSUBSCRIBE: http://www.evdl.org/help/index.html#usub http://lists.evdl.org/listinfo.cgi/ev-evdl.org For EV drag racing discussion, please use NEDRA (http://groups.yahoo.com/group/NEDRA)
