Hi Ben,

I once took two ThunderSky cells to 0 volts and was able to recover them
both.  I drove further than I should and had a pack that was rather severely
out of balance without realizing it.  I charged them carefully with fans on
them to keep them cool.  I expect they are still my weakest cells, but they
are still running in my car two years later.

I think you are probably OK having caught the cells while still above 1V.  I
would suggest changing out the BMS module causing problems before it does
something else.  I have kept my MiniBMS modules on my pack while having it
split for the winter before.  My only problem was the cells where the
MiniBMS had intermittent contact and wouldn't draw down the cells as much as
the others.  That left the pack slightly unbalanced.  I fixed that with a
small RC charger to balance the cells.

Mike

> -----Original Message-----
> From: [email protected] [mailto:[email protected]] On
> Behalf Of Ben Apollonio
> Sent: Saturday, March 02, 2013 6:38 PM
> To: Electric Vehicle Discussion List
> Subject: [EVDL] LiFePO4 over-discharge threshold
> 
> Does anyone know the 'do not go below' voltage at which the anode starts
to
> break down in LiFePO4?  I know it's somewhere at or below 2.0V but that's
> about all.
> 
> My car is parked for the winter.  The other day, I went to fire it up &
check on
> the batteries and my BMS refused to unlock it.  Some investigation
revealed
> that one of my ThunderSky cells was at 1.16V! (the rest were all at
3.345V).  It
> may have been at that level for weeks or only hours, I really have no
idea.
> So, after kicking myself for not disconnecting the BMS when I took the car
off
> the road, I disconnected everything (I once before saw this particular
module
> spontaneously turn on a balance resistor, but after several months without
> incident I thought I'd fixed the cause).  Today I came out to remove the
cell
> from the pack and discovered that it had recovered to 2.245V!  It may have
> helped that temperatures have been pretty cold here in New England.  I'm
> gently trying to nurse it back to health in an isolated area with a close
eye on
> voltage, temperature, and amp-hours, but I'd want to understand the
> chemistry better before I felt comfortable putting it back in the ca  r.
> 
> I tried looking around the EVDL archives and the internet but couldn't
turn up
> any numbers on the cell chemistry.  What's the voltage below which actual
> damage occurs?  Does the fact that the voltage recovered mean that it was
> not, in fact, over-discharged?  Or does it just mean that with things
> disconnected the chemistry stabilized at some minimal potential?
> 
> Thanks in advance,
> -Ben
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