Method combines x-ray absorption spectroscopy & supercomputer calculations

http://www.torquenews.com/1080/nissan-observes-electrons-fun-and-profit
Nissan observes electrons for fun and profit
By Aaron Turpen  2014-03-18

[image  
http://www.torquenews.com/sites/default/files/image-1080/nissan-leaf-battery-pack.jpg
Nissan LEAF battery cutaway
]

Nissan has developed an analysis technique for improving lithium-ion battery
durability. The analysis method they've developed could change electric
vehicle batteries for the better.

An advanced research project between Nissan's affiliate research arm, Nissan
Arc Ltd, in corroboration with universities in Japan has resulted in the
development of the world's first analysis method enabling direct observation
of electron activity in the cathode material of lithium-ion batteries during
charge and discharge.

The technique allows researchers and designers to see how the design and
materials within the battery affect its performance and paves the way
towards faster development of high-capacity batteries with better
durability.

The work, conducted by Nissan Arc, Tokyo University, Kyoto University, and
Osaka Prefecture University, provides an accurate depiction of how electrons
are emitted from certain elements that constitute the cathode material of
li-ion batteries. Takao Asami, Nissan senior vice president and president of
Nissan Arc Ltd., said: "Creating this analysis technique was a major step
toward the further development of high-capacity, next-generation lithium ion
batteries. It will play an important part in our future R&D aimed at
extending the driving range of future zero emission vehicles."

Existing analysis methods did not allow researchers to observe the movement
of electrons within the battery's cathode, limiting the ability to know how
materials and design were affecting capability. The maximize li-ion
batteries, for example, the maximum amount of lithium must e stored in the
electrode's active material, allowing it to generate the maximum number of
electrons. Being unable to accurately read electron activity within the
material means being able to maximize the material itself.

This new method combines x-ray absorption spectroscopy and first principle
calculation from Japan's Earth Simulator supercomputer. While x-ray
absorption has been used in the past on li-ion batteries, it was usually in
the K-spectrum. Nissan's team realized that the L-spectrum would be more
useful, allowing direct observation of cell reaction electrons.

For years scientists have wanted to understand the origin of electrons
during charging and discharging, and this newly-developed analysis method
finally makes it possible. Scientists can observe the exact phenomenon
inside a battery cell, especially the behavior of active materials of
electrodes, permitting further study of better-performing, longer-lasting
electrode materials. Nissan's team is now analyzing higher-capacity
electrode materials with the goal of increasing energy density by 150
percent.
[© torquenews.com]




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