[ref http://electric-vehicle-discussion-list.413529.n4.nabble.com/EVLN-24M-s-cheaper-li-ion-batteries-might-make-it-cost-effective-for-conversion-EV-use-td4682757.html ]
https://www.technologyreview.com/s/601500/24ms-batteries-could-better-harness-wind-and-solar-power/ 24M’s Batteries Could Better Harness Wind and Solar Power June 21, 2016 Elizabeth Woyke [images https://d267cvn3rvuq91.cloudfront.net/i/images/tr50.24m.1.x2760.jpg?sw=500&cx=0&cy=36&cw=1566&ch=2088 24M uses these batteries, which are packaged in laminated aluminum, as R&D prototypes. https://d267cvn3rvuq91.cloudfront.net/i/images/tr50.24m.2.x1000.jpg?sw=1024&cx=81&cy=0&cw=869&ch=667 A technician analyzes the powder that will go into the slurry that will become the battery’s cathode. The process involves mixing powdered materials (lithium iron phosphate, graphite) with a proprietary liquid electrolyte. https://d267cvn3rvuq91.cloudfront.net/i/images/tr50.24m.4.x999.jpg?sw=1024&cx=93&cy=0&cw=666&ch=666 The semisolid electrode has a dough-like consistency and can be deformed without failing or catching on fire. The company claims this high “abuse tolerance” makes its design the “safest lithium-ion battery ever made.” https://d267cvn3rvuq91.cloudfront.net/i/images/tr50.24m.3.x1000.jpg?sw=1024&cx=132&cy=13&cw=655&ch=654 https://d267cvn3rvuq91.cloudfront.net/i/images/tr50.24m.5.x1400.jpg?sw=1024&cx=0&cy=0&cw=1400&ch=933 This machine, developed in 2014 as part of 24M’s pilot manufacturing line, makes the battery’s anode and cathode separately, then combines them into one cell. The process takes less than two minutes. https://d267cvn3rvuq91.cloudfront.net/i/images/tr50.24m.7.x600.jpg?sw=1024&cx=75&cy=0&cw=400&ch=400 First the machine dispenses pieces of foil. Next it applies slurry. Then the machine adds the battery’s separator—porous plastic that prevents electrical short circuits—and joins the anode with its cathode mate. This creates a unit cell, which contains everything the battery needs to operate but lacks its final packaging. https://d267cvn3rvuq91.cloudfront.net/i/images/tr50.24m.6.x600_0.jpg?sw=1024&cx=80&cy=2&cw=398&ch=398 https://d267cvn3rvuq91.cloudfront.net/i/images/tr50.24m.9.x1300.jpg?sw=1024&cx=226&cy=0&cw=867&ch=867 Unit cells are stacked to increase battery capacity. Technicians then weld the cells’ tabs together to create a “stack cell” and vacuum-seal it inside an aluminum pouch. Welding and packaging are two of the few processes that 24M has not automated on its pilot line. https://d267cvn3rvuq91.cloudfront.net/i/images/tr50.24m.8.x600.jpg?sw=1024&cx=88&cy=0&cw=400&ch=400 https://d267cvn3rvuq91.cloudfront.net/i/images/tr50.24m.10.x1400.jpg?sw=1024&cx=0&cy=0&cw=1390&ch=933 Batteries wait before and after testing. It only takes a few hours to go from raw materials to batteries ready for testing, according to 24M. In a conventional lithium-ion factory that process would take about a week. ] The startup’s cheaper way to make lithium-ion batteries could make it cost-effective to store energy from renewable sources. Lithium-ion batteries power everything from smartphones to electric vehicles. They’re well suited to the job because they are smaller and lighter, charge faster, and last longer than other batteries. But they are also complex and thus costly to make, which has stymied mass adoption of electric transportation and large-scale energy storage. Yet-Ming Chiang thinks his startup 24M has the answer. The key is a semisolid electrode. In a conventional lithium--ion battery, many thin layers of electrodes are stacked or rolled together to produce a cell. “Lithium-ion batteries are the only product I know of besides baklava where you stack so many thin layers to build up volume,” says Chiang, who is a cofounder and chief scientist at 24M as well as a professor of materials science at MIT. “Our goal is to make a lithium-ion battery through the simplest process possible.” Chiang’s innovation, which was developed in his MIT lab, is an electrode formed by mixing powders with a liquid electrolyte to make a gooey slurry. The design enables 24M to increase the amount of energy-storing material in a battery and give it 15 to 25 percent more capacity than conventional lithium-ion batteries of the same size. The new design is also faster and cheaper to make. Typical large factories for making lithium-ion batteries cost about $100 million to build, in part because specialized machines are needed to coat, dry, cut, and compress the electrode film. Since its semisolid electrode doesn’t require these steps, 24M says, its batteries could be produced in one-fifth the time and in much smaller plants. If its technology succeeds, 24M could be among the first companies to reduce the cost of lithium-ion battery cells to less than $100 per kilowatt-hour, from $200 to $250 today. That is the point at which electric cars could compete on cost with internal-combustion vehicles. To hit that target by 2020, 24M must scale up from its existing pilot manufacturing line in Cambridge, Massachusetts, to high-volume fabrication. The company plans to build a factory in 2017, probably in partnership with a large industrial company, and launch its first product in early 2018. It hopes utilities will buy its batteries to store electricity from wind and solar farms and deliver power during peak-demand hours. The semisolid electrode has a dough-like consistency and can be deformed without failing or catching on fire. The company claims this high “abuse tolerance” makes its design the “safest lithium-ion battery ever made.” The company is also talking to electric--vehicle makers, but it considers EVs a secondary focus. It’s understandable that Chiang would tread carefully in that market. A123 Systems, a battery company he cofounded, filed for bankruptcy protection in 2012 after spending too much money building big battery plants to supply carmakers. In contrast, Chiang says, 24M’s manufacturing technologies are designed to be modular and more efficiently scaled up if necessary. 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