Found the solution - thought I would share.

To receive messages from two Simple Mail Transfer Protocol (SMTP) domains in 
Exchange 2000:

Contact the Internet Service Provider (ISP), and tell them to point both of 
the domain's MX records to the same Exchange 2000 computer.

For additional information A and MX records, click the article number below 
to view the article in the Microsoft Knowledge Base:
Q153001 XFOR: DNS MX Records and CNAMEs
Start Exchange System Manager.


Browse to Organization \Recipients\Recipient Policies.


Right-click Default Policy , and then click Properties .


Click the E-Mail Addresses tab, and then click New .


Click SMTP Address , and then click OK .


Verify that the This Exchange Organization is responsible for all mail 
delivery to this address check box has been selected.


In the Address box, type the new SMTP domain name (for example, companyb.com 
), and then click OK .


Click the E-Mail Addresses tab, and then click the new SMTP item to enable 
it.


Click the SMTP item, and then click Set as Primary .

This address is now the sender's reply SMTP address.


Click OK to apply the change.

You receive the following message:
Address generation for [SMTP] has been enabled for all newly created 
Recipients. Do you want to automatically add this Address Type to all 
existing Recipient e-mail addresses?
Click Yes if you want to generate this SMTP addresses for existing users. 
Otherwise, click No to give only newly created users this address.

NOTE : You may not want every user to have the secondary e-mail address. If 
you click No , you must create another recipient policy for those specific 
users who need this addresses, or manually add the address for each user.





>From: "James Mike" <[EMAIL PROTECTED]>
>Reply-To: "Exchange Discussions" <[EMAIL PROTECTED]>
>To: "Exchange Discussions" <[EMAIL PROTECTED]>
>Subject: Creating alias within w2000 require new domain?
>Date: Tue, 19 Mar 2002 09:24:40 -0600
>
>Let say your domain is @testing and you create an alias for your user that
>is @nottesting. You want this address to send mail to this infomation
>store. Is the only option in 2000 to create a new domain called
>nottesting. If so how would you do this.
>
>Eg: Mr x has email account [EMAIL PROTECTED]
>     Mr x has alias under this acount set to SMTP: [EMAIL PROTECTED]
>
>If anyone can give me any info it would be great.
>
>
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