Our dog was sprayed two years ago right in the chest- and I was told the smell could linger on him especially when wet, for several weeks.  We tried tomato juice, shampoo, etc., but, nothing worked very well.  He did get sprayed though, square in the chest, eyes watering, drooling, etc.  "Dogs About.com" has four recipes for shampoo mixtures you can try.  I tried the first recipe but, it was true, every time he got wet for weeks he smelled a little skunky!  Good luck though- it really stinks!

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