There is several reasons, why PSPad opens files as ANSI instead of UTF-8

1. there is no BOM and your UTF-8 doesn't contains any accented chars. In this
case content of ANSI and UTF-8 is same - there are no chars encoded in UTF-8

2. file is encoded in UTF-8 but there are some errors (e.g. file contains non
encoded chars). Typically exports from MySQL. In case you open this file as
UTF-8, you will lost some chars.

To force PSPad open file as UTF-8:
open your file
in the format menu click to UTF-8 (click it even UTF-8 is selected)
Use reload file (Ctrl+R)

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PSPad freeware editor http://www.pspad.com

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