I am currently using 5.07 (775) and can report the following:

When I open a CSS file, it cannot be edited via HTML/CSS code format or HTML/CSS
code compress. Both menu items are not selectable (gray). A workaround is to
create a new CSS file and copy the contents of the open file into it. Now the
above mentioned menu items can be selected.

In general I have to say that PSPad crashes extremely often for me in the last
years or can only be beeanden via an error message. Often when editing HTML
files. I have tried both the 64 and the 32Bit version.

With the current beta it seems to run more stable, but I had to remove the
version again, because the HTML preview does not work here. A window opens but
without content.

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Odpovedet emailem