PSPad cannot use the Python you installed from the Microsoft Store. The command
python in a console still works. That is a different way of starting it.

The Store copy keeps its files in a protected Windows package. Windows lets that
package start its own python.exe. It does not let another program, including
PSPad, load python3xx.dll from that package.

Python itself is in the C:\Program
Files\WindowsApps\PythonSoftwareFoundation.Python folder with special rights.

I am sorry, but Python installed from MS Store can!t be used as the scripting.

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