Dear PP Glad to have a first instance of a diesel fuel from improved pyrolysis, followed by esterification. (I hope you will get a gas chromatograph analysis). I wonder if there are also ethers (R-O-R) formed.
I drive a VW TDI diesel, best car I ever owned. Tom Reed Dr Thomas B Reed President, The Biomass Energy Foundation www.Woodgas.com On Jun 2, 2011, at 6:16 AM, "Pannirselvam P.V" <[email protected]> wrote: > Dear Ant and all list members > > From rapid pyrolysis oil from sugqr cane bagasse , syntheticoil called > bioflex oil was made in lab scale in Brazil from the aqueous part with > ethanol, they would form esters using catalyst known of organic Fisher > synthesis with significant yield and the quality of very good quality > gasoline ; This oil can be also used as fuel in diesel engine .The yield > is significant around 25 porcent of Bio oil; This not obtained from Tar > distillqtion , but this organic green chemical can be also applied to the > tar distilled products obtained by tar processing > > Pannirselvam P;V > Brazil > > On Tue, May 17, 2011 at 5:48 PM, Arnt Karlsen <[email protected]> wrote: > On Tue, 17 May 2011 07:35:32 -0400, Thomas wrote in message > <[email protected]>:roved > > > Dear ADK and all > > > > AD KARVE has an interesting idea here. I doubt if he or I have the > > equipment to follow it up, but hope some others here may do so. > > > > When you tear the lignin and celluloses in wood apart during > > pyrolysis, you briefly have a lot of VERY reactive species (free > > radicals) desperately looking for partners. > > ..that makes a lot of sense, and helps explain > my tar vapor flare performance. :o) > > > If they were supplied with a surplus of attractive partners, they > > would make many attractive combinations, some commercial today, and > > probably many others that would be attractive if available. > > > > If the diluent partner was methanol or ethanol, they would form > > esters (perfumes) ethers, and many other interesting compounds that > > I'm not enough organic chemist to list. > > > > I hope someone will give it a try... > > ..bubbling those tar vapors thru soap water and waste oil, creates an > amazingly stable emulsion with a 2 year shelf life IME, we made half > a dozen barrels that I understand the City of Stavanger took good care > of then they tore down the building around our experimental backyard. > > ..mixed a wee bit of my goo with saw dust, sand and dirt to clean up a > wee driveway oil slick spill, the problem was it also ate the asphalt. > > > > > Tom Reed > > > > Dr Thomas B Reed > > President, The Biomass Energy Foundation > > www.Woodgas.com > > > -- > ..med vennlig hilsen = with Kind Regards from Arnt Karlsen > ...with a number of polar bear hunters in his ancestry... > Scenarios always come in sets of three: > best case, worst case, and just in case. > > _______________________________________________ > Gasification mailing list > > to Send a Message to the list, use the email address > [email protected] > > to UNSUBSCRIBE or Change your List Settings use the web page > http://lists.bioenergylists.org/mailman/listinfo/gasification_lists.bioenergylists.org > > for more Gasifiers, News and Information see our web site: > http://gasifiers.bioenergylists.org/ > > > > -- > ************************************************ > P.V.PANNIRSELVAM > ASSOCIATE . PROF. > Research Group ,GPEC, Coordinator > Computer aided Cost engineering > > DEQ – Departamento de Engenharia Química > CT – Centro de Tecnologia / UFRN, Lagoa Nova – Natal/RN > Campus Universitário. CEP: 59.072-970 > North East,Brazil > ******************************************* > https://sites.google.com/a/biomassa.eq.ufrn.br/sites/ > and > http://ecosyseng.wetpaint.com/ > > > Fone ;Office > 84 3215-3769 , Ramal 210 > Home : 84 3217-1557 > > Mobile :558488145083 > > Email: > [email protected] > [email protected] > [email protected] > [email protected] > > > > _______________________________________________ > Gasification mailing list > > to Send a Message to the list, use the email address > [email protected] > > to UNSUBSCRIBE or Change your List Settings use the web page > http://lists.bioenergylists.org/mailman/listinfo/gasification_lists.bioenergylists.org > > for more Gasifiers, News and Information see our web site: > http://gasifiers.bioenergylists.org/
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